Immobilization of Ru(terpyridine)(2,6‐pyridinedicarboxylate) onto MCM‐41 and its catalysis in the oxidation of alcohols
作者： Yuecheng Zhang , Xiaochen Sun , Hongyu Zhang , Jiquan Zhao
DOI: 10.1002/AOC.3484
关键词:
摘要: The ruthenium complex Ru(terpyridine)(2,6-pyridinedicarboxylate) was successfully grafted onto MCM-41 using a multi-step grafting method. immobilized characterized thoroughly Fourier transform infrared, Raman, UV–visible diffuse reflectance and energy-dispersive X-ray spectroscopies, diffraction, N2 adsorption, scanning electron microscopy, thermogravimetric analysis inductively coupled plasma analysis. This showed excellent performance in the oxidation of various secondary alcohols to their corresponding ketones with tert-butyl hydroperoxide as oxidant under solvent-free conditions, had advantages easy recovery good reusability. Copyright © 2016 John Wiley & Sons, Ltd.
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