Electrosynthese en chimie organosilicique: preparation de phenyl- et benzyl-trimethylsilanes

作者: P. Pons , C. Biran , M. Bordeau , J. Dunogues , S. Sibille

DOI: 10.1016/0022-328X(87)80314-5

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摘要: Abstract In a single compartment cell fitted with sacrificial magnesium anode, electrochemical reduction of phenyl and benzyl halides in the presence trimethylchlorosilane gave corresponding phenyl- benzyl-silanes satisfactory yields. Under well chosen conditions, synthesis phenyltrimethylsilane from bromide or chloride was also found possible.

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