ELECTROLYTIC BEHAVIOR OF IODO- AND CHLOROSILANES. THE FORMATION OF SI-SI AND SI-SP-C BONDS

作者: Atsutaka Kunai , Osamu Ohnishi , Tomohiro Sakurai , Mitsuo Ishikawa

DOI: 10.1246/CL.1995.1051

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摘要: Electrolysis of iodosilanes with Al/Pt electrodes in pivalonitrile results the formation Si–Si bonds to give corresponding disilanes. On other hand, electrolysis various halosilanes such as iodo-, chloro-, and fluorosilanes Pt/Pt presence phenylacetylene leads Si–sp-carbon phenylethynylated products.

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