Achieving excellent electro-optic activity and thermal stability in poled polymers through an expeditious crosslinking process
作者： Zhengwei Shi , Jingdong Luo , Su Huang , Brent M. Polishak , Xing-Hua Zhou
DOI: 10.1039/C1JM14254B
关键词:
摘要: A series of highly efficient and thermally stable electro-optic (EO) polymers have been developed by poling crosslinking in situ the blend high glass-transition temperature (Tg) anthracene-containing acrylate-functionalized dendritic nonlinear optical (NLO) chromophores. By molecular engineering shape, nonlinearity, Tg, moieties chromophores polymers, resultant materials showed significantly enhanced EO activities (r33 values as 126 pm V−1 at 1310 nm) alignment stability (up to 200 °C). Poling efficiency these could be improved 35–50% using simplified lattice hardening protocols. The combined good processability, large activities, endow promising candidates for device exploration CMOS-based photonics.
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sci-hub.se 参考文章(35)
Seth R. Marder, Bernard Kippelen, Alex K.-Y. Jen, Nasser Peyghambarian, Design and synthesis of chromophores and polymers for electro-optic and photorefractive applications Nature. ,vol. 388, pp. 845- 851 ,(1997) , 10.1038/42190
Larry R. Dalton, Philip A. Sullivan, Denise H. Bale, Electric field poled organic electro-optic materials: state of the art and future prospects. Chemical Reviews. ,vol. 110, pp. 25- 55 ,(2010) , 10.1021/CR9000429
Po Dong, Shirong Liao, Dazeng Feng, Hong Liang, Dawei Zheng, Roshanak Shafiiha, Cheng-Chih Kung, Wei Qian, Guoliang Li, Xuezhe Zheng, Ashok V. Krishnamoorthy, Mehdi Asghari, Low V_pp, ultralow-energy, compact, high-speed silicon electro-optic modulator Optics Express. ,vol. 17, pp. 22484- 22490 ,(2009) , 10.1364/OE.17.022484
R. D. Miller, D. M. Burland, M. Jurich, V. Y. Lee, C. R. Moylan, J. I. Thackara, R. J. Twieg, T. Verbiest, W. Volksen, Donor-Embedded Nonlinear Optical Side Chain Polyimides Containing No Flexible Tether: Materials of Exceptional Thermal Stability for Electrooptic Applications Macromolecules. ,vol. 28, pp. 4970- 4974 ,(1995) , 10.1021/MA00118A026
Tae-Dong Kim, Jingdong Luo, Yanqing Tian, Jae-Won Ka, Neil M. Tucker, Marnie Haller, Jae-Wook Kang, Alex K.-Y. Jen, Diels−Alder “Click Chemistry” for Highly Efficient Electrooptic Polymers Macromolecules. ,vol. 39, pp. 1676- 1680 ,(2006) , 10.1021/MA052087K
C. C. Teng, H. T. Man, Simple reflection technique for measuring the electro‐optic coefficient of poled polymers Applied Physics Letters. ,vol. 56, pp. 1734- 1736 ,(1990) , 10.1063/1.103107
Tian-An Chen, Alex K.-Y. Jen, Yongming Cai, Facile Approach to Nonlinear Optical Side-Chain Aromatic Polyimides with Large Second-Order Nonlinearity and Thermal Stability Journal of the American Chemical Society. ,vol. 117, pp. 7295- 7296 ,(1995) , 10.1021/JA00132A050
Naiheng Song, Liqiu Men, Jian Ping Gao, Yaowen Bai, Andrew M. R. Beaudin, Guomin Yu, Zhi Yuan Wang, Cross-Linkable Zwitterionic Polyimides with High Electrooptic Coefficients at Telecommunication Wavelengths Chemistry of Materials. ,vol. 16, pp. 3708- 3713 ,(2004) , 10.1021/CM0493851
S. Liu, M.A. Haller, H. Ma, L.R. Dalton, S.-H. Jang, A.K.-Y. Jen, Focused microwave-assisted synthesis of 2,5-dihydrofuran derivatives as electron acceptors for highly efficient nonlinear optical chromophores Advanced Materials. ,vol. 15, pp. 603- 607 ,(2003) , 10.1002/ADMA.200304813
Hui Wang, Zhikuan Lu, Samuel J. Lord, Katherine A. Willets, Jeffrey A. Bertke, Scott D. Bunge, W.E. Moerner, Robert J. Twieg, The influence of tetrahydroquinoline rings in dicyanomethylenedihydrofuran (DCDHF) single-molecule fluorophores Tetrahedron. ,vol. 63, pp. 103- 114 ,(2007) , 10.1016/J.TET.2006.10.044