Crystal Structures and Expansion Anomalies of MnO, MnS, FeO, Fe3O4 Between 100°K and 200°K

作者: Bennett S. Ellefson , Nelson W. Taylor

DOI: 10.1063/1.1749421

关键词:

摘要: (1) Determinations have been made of structure type and lattice constants MnO, MnS, FeO Fe3O4 at temperatures near those which these substances show specific heat anomalies. (2) No major changes were apparent in the x‐ray patterns. All structures are cubic all investigated temperatures. Lattice constant data indicate similarity abnormal expansion behavior MnS MnO Fe3O4. (3) The anomalies probably due to electron transitions within certain atoms crystal may be analogous metallic iron 765°C, or quartz 575°C.

参考文章(12)
J. Disch, Über die Wärmeausdehnung einiger Stoffe. II European Physical Journal. ,vol. 5, pp. 173- 175 ,(1921) , 10.1007/BF01329250
F. Simon, Cl. v. Simson, Ein Umwandlungspunkt der Ammoniumsalze zwischen -30 und -40 Grad Naturwissenschaften. ,vol. 14, pp. 880- 881 ,(1926) , 10.1007/BF01490355
Nelson W. Taylor, AN X‐RAY CAMERA FOR POWDER DIAGRAMS AT ANY TEMPERATURE Review of Scientific Instruments. ,vol. 2, pp. 751- 755 ,(1931) , 10.1063/1.1748749
J. C. Southard, R. T. Milner, S. B. Hendricks, Low Temperature Specific Heats: III. Molecular Rotation in Crystalline Primary Normal Amyl Ammonium Chloride The Journal of Chemical Physics. ,vol. 1, pp. 95- 102 ,(1933) , 10.1063/1.1749225
Linus Pauling, The Rotational Motion of Molecules in Crystals Physical Review. ,vol. 36, pp. 430- 443 ,(1930) , 10.1103/PHYSREV.36.430
Franz Simon, Untersuchungen über die spezifische Wärme bei tiefen Temperaturen Annalen der Physik. ,vol. 373, pp. 241- 280 ,(1922) , 10.1002/ANDP.19223731103
S. B. Hendricks, E. Posnjak, F. C. Kracek, MOLECULAR ROTATION IN THE SOLID STATE. THE VARIATION OF THE CRYSTAL STRUCTURE OF AMMONIUM NITRATE WITH TEMPERATURE Journal of the American Chemical Society. ,vol. 54, pp. 2766- 2786 ,(1932) , 10.1021/JA01346A020
L. H. Adams, CALIBRATION TABLES FOR COPPER-CONSTANTAN AND PLATINUM-PLATINRHODIUM THERMOELEMENTS. Journal of the American Chemical Society. ,vol. 36, pp. 65- 72 ,(1914) , 10.1021/JA02178A007
Russell W. Millar, THE HEAT CAPACITIES AT LOW TEMPERATURES OF “FERROUS OXIDE,” MAGNETITE AND CUPROUS AND CUPRIC OXIDES1 Journal of the American Chemical Society. ,vol. 51, pp. 215- 222 ,(1929) , 10.1021/JA01376A026