Characterization of a Saturated and Flexible Aliphatic Polyol Anion Receptor
作者： Alireza Shokri , Jacob Schmidt , Xue-Bin Wang , Steven R Kass , None
DOI: 10.1021/JA3075456
关键词:
摘要: Nature employs flexible molecules to bind anions in a variety of physiologically important processes whereas supramolecular chemists have been designing rigid substrates that minimize or eliminate intramolecular hydrogen bond interactions carry out anion recognition. Herein, the association polyhydroxy alkane with chloride ion is described and bound receptor characterized by infrared photoelectron spectroscopy gas phase, computations, its binding constant as function temperature acetonitrile.
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