Microwave-accelerated homogeneous catalysis in organic chemistry.

作者: Mats Larhed , Christina Moberg , Anders Hallberg

DOI: 10.1021/AR010074V

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摘要: The efficiency of microwave flash heating in accelerating organic transformations (reaction times reduced from days and hours to minutes seconds) has recently been proven several different fields chemistry. This specific account mainly summarizes our own experiences developing rapid, robust, selective microwave-assisted transition metal-catalyzed homogeneous reactions. Applications include Heck couplings, cross-couplings, asymmetric substitutions. science green chemistry was developed meet the increasing demand for environmentally benign chemical processes. We believe combination metal catalysis will be importance search laboratory-scale synthesis.

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