On the origin of the non-faradaic electrochemical modification of catalytic activity (NEMCA) phenomena. Oxygen isotope exchange on Pt electrode in cell with solid oxide electrolyte
作者： V. A. Sobyanin , V. I. Sobolev , V. D. Belyaev , O. A. Mar'ina , A. K. Demin
DOI: 10.1007/BF00769508
关键词:
摘要: Homomolecular oxygen exchange on Pt electrode in a zirconia electrochemical cell was studied. It found that the current passing through (O2− pumping electrolyte) does not change rate of with respect to its open circuit value, fact indicates strength chemisorptive bond is invariant under and closed conditions.
springer.com
sci-hub.se 参考文章(12)
O. A. Mar'ina, V. A. Sobyanin, The effect of electrochemical oxygen pumping on the rate of CO oxidation on Au electrode-catalyst Catalysis Letters. ,vol. 13, pp. 61- 69 ,(1992) , 10.1007/BF00770948
V.I. Sobolev, V.A. Sobyanin, A.V. Pashis, A.V. Kalinkin, G.I. Panov, Oxygen isotope exchange on Pt(100) monocrystal Surface Science. ,vol. 173, pp. 498- 502 ,(1986) , 10.1016/0039-6028(86)90205-0
Yehuda L. Sandler, D. D. Durigon, ISOTOPIC EXCHANGE OF OXYGEN ON PLATINUM POWDER. The Journal of Physical Chemistry. ,vol. 72, pp. 1051- 1057 ,(1968) , 10.1021/J100849A047
V. I. Sobolev, G. I. Panov, A. S. Kharitonov, Rate of14N2 desorption from the surfaces of nitrides in the presence and absence of15N2 in the gas phase Reaction Kinetics and Catalysis Letters. ,vol. 29, pp. 433- 441 ,(1985) , 10.1007/BF02068538
Vladimir D. Belyaev, Vladimir A. Sobyanin, Anatolii K. Demin, Aleksandr S. Lipilin, Valerii E. Zapesotskii, The Influence of Electrochemical Pumping of Oxygen through a Solid Oxide Electrolyte on the Catalytic Properties of Platinum in Methane Oxidation Mendeleev Communications. ,vol. 1, pp. 53- 55 ,(1991) , 10.1070/MC1991V001N02ABEH000031
E. J. L. Schouler, M. Kleitz, Electrocatalysis and inductive effects at the gas, Pt/stabilized zirconia interface Journal of The Electrochemical Society. ,vol. 134, pp. 1045- 1050 ,(1987) , 10.1149/1.2100614
I. Toyoshima, G. A. Somorjai, Heats of Chemisorption of O2, H2, CO, CO2, and N2 on Polycrystalline and Single Crystal Transition Metal Surfaces Catalysis Reviews-science and Engineering. ,vol. 19, pp. 105- 159 ,(1979) , 10.1080/03602457908065102
C.G. Vayenas, S. Bebelis, I.V. Yentekakis, H.-G. Lintz, Non-faradaic electrochemical modification of catalytic activity: A status report Catalysis Today. ,vol. 11, pp. 303- 438 ,(1992) , 10.1016/0920-5861(92)80002-5
T. I. Politova, V. A. Sobyanin, V. D. Belyaev, Ethylene hydrogenation in electrochemical cell with solid proton-conducting electrolyte Reaction Kinetics and Catalysis Letters. ,vol. 41, pp. 321- 326 ,(1990) , 10.1007/BF02097888
Atsumu Ozaki, Isotopic studies of heterogeneous catalysis ,(1977)