ON THE NATURE OF NON-FARADAIC CATALYSIS ON METAL ELECTRODES

作者: V. A. Sobyanin , V. D. Belyaev

DOI: 10.1007/BF02069080

关键词:

摘要: Non-Faradaic change of the rate catalytic oxidation on polarization catalyst electrode deposited a solid oxygen-conducting electrolyte has been shown to result from chain reaction mechanism involving electrochemically generated oxygen species.

参考文章(8)
O. A. Mar'ina, V. A. Sobyanin, The effect of electrochemical oxygen pumping on the rate of CO oxidation on Au electrode-catalyst Catalysis Letters. ,vol. 13, pp. 61- 69 ,(1992) , 10.1007/BF00770948
C. G. Vayenas, S. Bebelis, S. Ladas, Dependence of catalytic rates on catalyst work function Nature. ,vol. 343, pp. 625- 627 ,(1990) , 10.1038/343625A0
V. A. Sobyanin, V. I. Sobolev, V. D. Belyaev, A. K. Demin, O. A. Mar'ina, OXYGEN ISOTOPE EXCHANGE OVER A PT ELECTRODE IN A CELL WITH SOLID OXIDE ELECTROLYTE Reaction Kinetics and Catalysis Letters. ,vol. 47, pp. 327- 331 ,(1992) , 10.1007/BF02137668
C.G. Vayenas, S. Bebelis, I.V. Yentekakis, H.-G. Lintz, Non-faradaic electrochemical modification of catalytic activity: A status report Catalysis Today. ,vol. 11, pp. 303- 438 ,(1992) , 10.1016/0920-5861(92)80002-5
B. C. Nguyen, L. M. Rincon‐Rubio, D. M. Mason, Mechanism of the Electrocatalytic Reduction of Oxygen in a Tubular Solid Oxide Electrolyte Flow Reactor Journal of The Electrochemical Society. ,vol. 133, pp. 1860- 1869 ,(1986) , 10.1149/1.2109036
V. A. Sobyanin, V. I. Sobolev, V. D. Belyaev, O. A. Mar'ina, A. K. Demin, A. S. Lipilin, On the origin of the non-faradaic electrochemical modification of catalytic activity (NEMCA) phenomena. Oxygen isotope exchange on Pt electrode in cell with solid oxide electrolyte Catalysis Letters. ,vol. 18, pp. 153- 164 ,(1993) , 10.1007/BF00769508