Rapid Combustion Synthesis of Light-Storing-Emitting Material SrAl2O4 : Eu2 + , Dy3 + and Its Spectral Characteristics

作者: Yuqi Zhang , Zhonglin Chen , Zhiming Zhou

DOI: 10.1149/1.2170547

关键词:

摘要: Light-storing-emitting materials composed of SrAl 2 O 4 :Eu 2+ ,Dy 3+ are synthesized via the wet combustion method, and fluffy resultants obtained easily pulverized into powder samples. The fluorescent spectra sample show same characteristics as those samples fabricated by dry method. But phosphorescent spectrum shows uniquely two peaks at 506 535 nm, with intensity nm stronger than that which is presumably ascribed to splitting 5d orbitals Eu groups, eg t 2g . lower-energy level has equal d z2 x2-y2 , while higher-energy three xy xz yz More photons stored released from higher orbitals, resulting in a peak spectrum.

参考文章(12)
Kee-Sun Sohn, Duk Hyun Park, Ji Sik Kim, Luminescence of Pulsed-Laser-Deposited SrAl2O4 : Eu ,Dy Thin Film and Its Role as a Stress Indicator Journal of The Electrochemical Society. ,vol. 152, ,(2005) , 10.1149/1.2012947
H. B. Yuan, W. Jia, S. A. Basun, L. Lu, R. S. Meltzer, W. M. Yen, The Long‐Persistent Photoconductivity of SrAl2 O 4 : Eu2 + , Dy3 + Single Crystals Journal of The Electrochemical Society. ,vol. 147, pp. 3154- 3156 ,(2000) , 10.1149/1.1393875
T. Matsuzawa, Y. Aoki, N. Takeuchi, Y. Murayama, A New Long Phosphorescent Phosphor with High Brightness, SrAl2 O 4 : Eu2 + , Dy3 + Journal of The Electrochemical Society. ,vol. 143, pp. 2670- 2673 ,(1996) , 10.1149/1.1837067
Yuanhua Lin, Zhongtai Zhang, Feng Zhang, Zilong Tang, Qingming Chen, Preparation of the ultrafine SrAl2O4:Eu,Dy needle-like phosphor and its optical properties Materials Chemistry and Physics. ,vol. 65, pp. 103- 106 ,(2000) , 10.1016/S0254-0584(00)00222-4
Yuanhua Lin, Zilong Tang, Zhongtai Zhang, Preparation of long-afterglow Sr4Al14O25-based luminescent material and its optical properties Materials Letters. ,vol. 51, pp. 14- 18 ,(2001) , 10.1016/S0167-577X(01)00257-9
Zilong Tang, Feng Zhang, Zhongtai Zhang, Chuanyong Huang, Yuanhua Lin, Luminescent properties of SrAl2O4: Eu, Dy material prepared by the gel method Journal of The European Ceramic Society. ,vol. 20, pp. 2129- 2132 ,(2000) , 10.1016/S0955-2219(00)00092-3
Yuanhua Lin, Zhongtai Zhang, Zilong Tang, Junying Zhang, Zishan Zheng, Xiao Lu, The characterization and mechanism of long afterglow in alkaline earth aluminates phosphors co-doped by Eu2O3 and Dy2O3 Materials Chemistry and Physics. ,vol. 70, pp. 156- 159 ,(2001) , 10.1016/S0254-0584(00)00500-9
Weiyi Jia, Huabiao Yuan, Lizhu Lu, Huimin Liu, William M Yen, Crystal growth and characterization of Eu2+, Dy3+: SrAl2O4 and Eu2+, Nd3+ : CaAl2O4 by the lhpg method Journal of Crystal Growth. ,vol. 200, pp. 179- 184 ,(1999) , 10.1016/S0022-0248(98)01099-9
Weiyi Jia, Huabiao Yuan, Lizhu Lu, Huimin Liu, W.M. Yen, Phosphorescent dynamics in SrAl2O4: Eu2 +, Dy3 + single crystal fibers Journal of Luminescence. ,vol. 76-77, pp. 424- 428 ,(1998) , 10.1016/S0022-2313(97)00230-5
T. Katsumata, T. Nabae, K. Sasajima, T. Matsuzawa, Growth and characteristics of long persistent SrAl2O4- and CaAl2O4-based phosphor crystals by a floating zone technique Journal of Crystal Growth. ,vol. 183, pp. 361- 365 ,(1998) , 10.1016/S0022-0248(97)00308-4