In-situ X-ray Absorption Fine Structure Study of TiO2 Nanoparticles under Ultraviolet Light

作者: Jong-Sul Jeon , Byung-Hyuk Kim , Chang-In Park , Soo-Young Seo , Changha Kwak

DOI: 10.1143/JJAP.49.031105

关键词:

摘要: The local structural properties of TiO2 nanoparticles (NPs) were investigated under ultraviolet light (UV) using in-situ X-ray absorption fine structure measurements at the Ti K edge. XAFS analysis showed that bond lengths atomic pairs distorted by 0.1 A and Debye–Waller factors increased substantially UV light, compared with those no light. These results suggested changes caused photocatalyst reactivity oxygen atoms in NPs. Unlike other techniques, is sensitive to detect during photocatalytic reactivity.

参考文章(21)
A.A. Battiston, J.H. Bitter, D.C. Koningsberger, XAFS characterization of the binuclear iron complex in overexchanged Fe/ZSM5 – structure and reactivity Catalysis Letters. ,vol. 66, pp. 75- 79 ,(2000) , 10.1023/A:1019079002486
S.-W. Han, E. A. Stern, D. Haskel, A. R. Moodenbaugh, Local structure in the stripe phase of La 1.6- x Sr x Nd 0.4 CuO 4 Physical Review B. ,vol. 66, pp. 094101- ,(2002) , 10.1103/PHYSREVB.66.094101
W. Li, A. I. Frenkel, J. C. Woicik, C. Ni, S. Ismat Shah, Dopant location identification in Nd3+ doped TiO2 nanoparticles Physical Review B. ,vol. 72, pp. 155315- ,(2005) , 10.1103/PHYSREVB.72.155315
U. Bach, D. Lupo, P. Comte, J. E. Moser, F. Weissörtel, J. Salbeck, H. Spreitzer, M. Grätzel, Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies Nature. ,vol. 395, pp. 583- 585 ,(1998) , 10.1038/26936
J Purans, A Azens, CG Granqvist, X-ray absorption study of Ce-Ti oxide films Electrochimica Acta. ,vol. 46, pp. 2055- 2058 ,(2001) , 10.1016/S0013-4686(01)00415-7
Andrew J. Berry, Andrew M. Walker, Jörg Hermann, Hugh St.C. O'Neill, Garry J. Foran, Julian D. Gale, Titanium substitution mechanisms in forsterite Chemical Geology. ,vol. 242, pp. 176- 186 ,(2007) , 10.1016/J.CHEMGEO.2007.03.010
Yu Lin, Photocatalytic activity of TiO2 nanowire arrays Materials Letters. ,vol. 62, pp. 1246- 1248 ,(2008) , 10.1016/J.MATLET.2007.08.021
Hua Gui Yang, Cheng Hua Sun, Shi Zhang Qiao, Jin Zou, Gang Liu, Sean Campbell Smith, Hui Ming Cheng, Gao Qing Lu, None, Anatase TiO(2) single crystals with a large percentage of reactive facets Nature. ,vol. 453, pp. 638- 641 ,(2008) , 10.1038/NATURE06964
E.A. Stern, M. Newville, B. Ravel, Y. Yacoby, D. Haskel, The UWXAFS analysis package : philosophy and details Physica B-condensed Matter. ,vol. 208, pp. 117- 120 ,(1995) , 10.1016/0921-4526(94)00826-H
A. L. Ankudinov, B. Ravel, J. J. Rehr, S. D. Conradson, REAL-SPACE MULTIPLE-SCATTERING CALCULATION AND INTERPRETATION OF X-RAY-ABSORPTION NEAR-EDGE STRUCTURE Physical Review B. ,vol. 58, pp. 7565- 7576 ,(1998) , 10.1103/PHYSREVB.58.7565