Properties and characteristics of squarylium-based chemosensors for Hg2+

作者: Eun-Mi Lee , Seon-Yeong Gwon , Young-A Son , Sung-Hoon Kim

DOI: 10.1080/10610278.2012.752086

关键词:

摘要: A chemosensor based on symmetrical squarylium (SQ) dye, 2,4-bis((3,3-dimethylindolin-2-ylidene)methyl)cyclobutane-1,3-bis(olate), was synthesised and its cation-sensing properties in acetonitrile were investigated by UV–vis spectroscopy. Upon the addition of Hg2+, solution SQ dye showed clear colour change. The absorption studies also indicate a higher affinity Hg2+ towards formation 2:1 complexes, which is good agreement with experimental results. selective detection symmetrical-SQ unit gave rise to significant decrease at λmax 650 solution.

参考文章(33)
B. Delley, From molecules to solids with the DMol3 approach Journal of Chemical Physics. ,vol. 113, pp. 7756- 7764 ,(2000) , 10.1063/1.1316015
Sung Hoon Kim, Sun Kyung Han, Jae Joon Kim, Woo Taik Lim, Nam Ho Heo, Kwang Nak Koh, Crystal Structure of a photoconductive dithiosquarylium dye: 2,4-Bis(1,3,3-trimethyl-2-indolinylidenemethyl) cyclobutenediylium-1,3-dithiolate Dyes and Pigments. ,vol. 39, pp. 259- 266 ,(1998) , 10.1016/S0143-7208(98)00012-6
H.-E. Sprenger, W. Ziegenbein, The Cyclobutenediylium Cation, a Novel Chromophore from Squaric Acid Angewandte Chemie. ,vol. 6, pp. 553- 554 ,(1967) , 10.1002/ANIE.196705531
A. Daniel Boese, Nicholas C. Handy, A new parametrization of exchange–correlation generalized gradient approximation functionals Journal of Chemical Physics. ,vol. 114, pp. 5497- 5503 ,(2001) , 10.1063/1.1347371
Chris Orvig, Michael J. Abrams, Medicinal inorganic chemistry: introduction. Chemical Reviews. ,vol. 99, pp. 2201- 2204 ,(1999) , 10.1021/CR980419W
Reagan McRae, Pritha Bagchi, S. Sumalekshmy, Christoph J. Fahrni, In Situ Imaging of Metals in Cells and Tissues Chemical Reviews. ,vol. 109, pp. 4780- 4827 ,(2009) , 10.1021/CR900223A
Richard A. Bissell, A. Prasanna de Silva, H. Q. Nimal Gunaratne, P. L. Mark Lynch, Glenn E. M. Maguire, K. R. A. Samankumara Sandanayake, Molecular fluorescent signalling with ‘fluor–spacer–receptor’ systems: approaches to sensing and switching devices via supramolecular photophysics Chem. Soc. Rev.. ,vol. 21, pp. 187- 195 ,(1992) , 10.1039/CS9922100187
Emily L. Que, Dylan W. Domaille, Christopher J. Chang, Metals in Neurobiology: Probing Their Chemistry and Biology with Molecular Imaging Chemical Reviews. ,vol. 108, pp. 1517- 1549 ,(2008) , 10.1021/CR078203U
Sung Hoon Kim, Seok Hwan Hwang, Electrochromic Properties of Functional Squarylium Dyes Dyes and Pigments. ,vol. 36, pp. 139- 148 ,(1998) , 10.1016/S0143-7208(97)00006-5