Diiron azadithiolates as models for the [FeFe]-hydrogenase active site and paradigm for the role of the second coordination sphere.
DOI: 10.1021/ACS.ACCOUNTS.5B00177
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摘要: … Overall, the pdt complex allows for perfect control experiments in studying the role of the second coordination sphere because the first coordination spheres are identical. …
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Hideaki Ogata, Koji Nishikawa, Wolfgang Lubitz, Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase Nature. ,vol. 520, pp. 571- 574 ,(2015) , 10.1038/NATURE14110
Agnieszka Adamska-Venkatesh, Trevor R. Simmons, Judith F. Siebel, Vincent Artero, Marc Fontecave, Edward Reijerse, Wolfgang Lubitz, Artificially maturated [FeFe] hydrogenase from Chlamydomonas reinhardtii: a HYSCORE and ENDOR study of a non-natural H-cluster Physical Chemistry Chemical Physics. ,vol. 17, pp. 5421- 5430 ,(2015) , 10.1039/C4CP05426A
Jane L. Stanley, Zachariah M. Heiden, Thomas B. Rauchfuss, Scott R. Wilson, Luca De Gioia, Guiseppe Zampella, Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases. Organometallics. ,vol. 27, pp. 119- 125 ,(2008) , 10.1021/OM7009599
Brian C. Manor, Mark R. Ringenberg, Thomas B. Rauchfuss, Borane-Protected Cyanides as Surrogates of H-Bonded Cyanides in [FeFe]-Hydrogenase Active Site Models Inorganic Chemistry. ,vol. 53, pp. 7241- 7247 ,(2014) , 10.1021/IC500470Z
Giuseppe Zampella, Piercarlo Fantucci, Luca De Gioia, DFT characterization of the reaction pathways for terminal- to μ-hydride isomerisation in synthetic models of the [FeFe]-hydrogenase active site Chemical Communications. ,vol. 46, pp. 8824- 8826 ,(2010) , 10.1039/C0CC02821E
Frédéric Gloaguen, Thomas B. Rauchfuss, Small molecule mimics of hydrogenases: hydrides and redox Chemical Society Reviews. ,vol. 38, pp. 100- 108 ,(2009) , 10.1039/B801796B
Joshua D. Lawrence, Hongxiang Li, Thomas B. Rauchfuss, Marc Bénard, Marie-Madeleine Rohmer, Diiron Azadithiolates as Models for the Iron-Only Hydrogenase Active Site: Synthesis, Structure, and Stereoelectronics Angewandte Chemie International Edition. ,vol. 40, pp. 1768- 1771 ,(2001) , 10.1002/1521-3773(20010504)40:9<1768::AID-ANIE17680>3.0.CO;2-E
Michael Schmidt, Stephen M. Contakes, Thomas B. Rauchfuss, First Generation Analogues of the Binuclear Site in the Fe-Only Hydrogenases: Fe2(μ-SR)2(CO)4(CN)22- Journal of the American Chemical Society. ,vol. 121, pp. 9736- 9737 ,(1999) , 10.1021/JA9924187
Caiping Liu, Jamie N. T. Peck, Joseph A. Wright, Christopher J. Pickett, Michael B. Hall, Density Functional Calculations on Protonation of the [FeFe]-Hydrogenase Model Complex Fe2(μ-pdt)(CO)4(PMe3)2 and Subsequent Isomerization Pathways European Journal of Inorganic Chemistry. ,vol. 2011, pp. 1080- 1093 ,(2011) , 10.1002/EJIC.201001085
Alban Le Cloirec, Sian C. Davies, David J. Evans, David L. Hughes, Christopher J. Pickett, Stephen P. Best, Stacey Borg, A di-iron dithiolate possessing structural elements of the carbonyl/cyanide sub-site of the H-centre of Fe-only hydrogenase Chemical Communications. pp. 2285- 2286 ,(1999) , 10.1039/A906391I