Theoretical treatment of redox processes involving lanthanide(II) compounds: reactivity of organosamarium(II) and organothulium(II) complexes with CO2 and pyridine.
作者： Stéphanie Labouille , François Nief , Laurent Maron
DOI: 10.1021/JP205144H
关键词:
摘要: An effective methodology to deal with the theoretical treatment on redox chemistry of divalent organolanthanide complexes is reported and has been tested two representative substrates, pyridine CO2, different metals (samarium thulium). influence ancillary ligands, namely, C5Me5 (Cp*) or (2,3,4,5-tetramethylphospholyl) (Tmp), one- two-electron oxidation processes observed. The results are in excellent agreement experimental observations indicating efficiency method.
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