A multidimensional gas chromatography method for the analysis of hydrogen sulfide in crude oil and crude oil headspace.
作者： Nicole E. Heshka , Darcy B. Hager
关键词:
摘要: Two-dimensional heart-cutting gas chromatography is used to analyze dissolved hydrogen sulfide in crude samples. Liquid samples are separated first on an HP-PONA column, and the light sulfur gases heart-cut a GasPro where from other detected with chemiluminescence detector. Heart-cutting accomplished use of Deans switch. Backflushing columns after detection eliminates any problems caused by high-boiling hydrocarbons Dissolved quantified 14 oil samples, results shown this work. The method also applicable analysis headspace over Gas measurements compared liquid for same sample set. chromatographic system design discussed, chromatograms representative shown.
sci-hub.se 参考文章(25)
D. R. Deans, A new technique for heart cutting in gas chromatography [1] Chromatographia. ,vol. 1, pp. 18- 22 ,(1968) , 10.1007/BF02259005
Jim Luong, Ronda Gras, Robert A. Shellie, Hernan J. Cortes, Applications of planar microfluidic devices and gas chromatography for complex problem solving. Journal of Separation Science. ,vol. 36, pp. 182- 191 ,(2013) , 10.1002/JSSC.201200789
Fanny Hildmann, Günther Kempe, Karl Speer, Application of the precolumn back-flush technology in pesticide residue analysis: a practical view. Journal of Separation Science. ,vol. 36, pp. 2128- 2135 ,(2013) , 10.1002/JSSC.201300007
Philip J. Marriott, Sung-Tong Chin, Bussayarat Maikhunthod, Hans-Georg Schmarr, Stefan Bieri, Multidimensional gas chromatography Trends in Analytical Chemistry. ,vol. 34, pp. 1- 21 ,(2012) , 10.1016/J.TRAC.2011.10.013
Bin Liu, Yongming Chai, Yanpeng Li, Anjie Wang, Yunqi Liu, Chenguang Liu, Kinetic investigation of the effect of H2S in the hydrodesulfurization of FCC gasoline Fuel. ,vol. 123, pp. 43- 51 ,(2014) , 10.1016/J.FUEL.2014.01.055
Houyi Ma, Xiaoliang Cheng, Guiqiu Li, Shenhao Chen, Zhenlan Quan, Shiyong Zhao, Lin Niu, The influence of hydrogen sulfide on corrosion of iron under different conditions Corrosion Science. ,vol. 42, pp. 1669- 1683 ,(2000) , 10.1016/S0010-938X(00)00003-2
John V. Seeley, Recent advances in flow-controlled multidimensional gas chromatography. Journal of Chromatography A. ,vol. 1255, pp. 24- 37 ,(2012) , 10.1016/J.CHROMA.2012.01.027
Pedro Araujo, Key aspects of analytical method validation and linearity evaluation. Journal of Chromatography B. ,vol. 877, pp. 2224- 2234 ,(2009) , 10.1016/J.JCHROMB.2008.09.030
Xinwei Yan, Unique selective detectors for gas chromatography: nitrogen and sulfur chemiluminescence detectors. Journal of Separation Science. ,vol. 29, pp. 1931- 1945 ,(2006) , 10.1002/JSSC.200500507
Frank P. Di Sanzo, William Bray, Birbal Chawla, Determination of the sulfur components of gasoline streams by capillary column gas chromatography with sulfur chemiluminescence detection Hrc-journal of High Resolution Chromatography. ,vol. 17, pp. 255- 258 ,(1994) , 10.1002/JHRC.1240170412