A rapid evaluation of vanadium oxide and manganese oxide as battery materials with a micro-electrochemistry technique

作者: V. Vivier , S. Belair , C. Cachet-Vivier , J.-Y. Nedelec , L.T. Yu

DOI: 10.1016/S0378-7753(01)00822-9

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摘要: Abstract The electrochemical behavior of vanadium oxide V 2 O 5 and bismuth doped manganese Bi–MnO as battery materials was studied with a cavity microelectrode (CME). This technique, which allows working on very few amount material, appears to be suitable when high scan rates are used. Thus, it is possible perform many hundreds cycles in short time. performances pure lithium insertion material inorganic media, examined CME appear excellent whereas poor results were obtained Bi MnO , for the mechanism proceeds via dissolution.

参考文章(21)
H. Ouboumour, C. Cachet, M. Bodé, L. T. Yu, Manganese Dioxide Rechargeability in Aqueous Media The Combination of Oxygen‐Regeneration with Electrochemical Regeneration Journal of The Electrochemical Society. ,vol. 142, pp. 1061- 1068 ,(1995) , 10.1149/1.2044132
M. Bodé, C. Cachet, S. Bach, J.‐P. Pereira‐Ramos, J. C. Ginoux, L. T. Yu, Rechargeability of MnO2 in KOH Media Produced by Decomposition of Dissolved KMnO4 and Bi ( NO 3 ) 3 Mixtures I. Mn‐Bi Complexes Journal of The Electrochemical Society. ,vol. 144, pp. 792- 801 ,(1997) , 10.1149/1.1837491
V. Vivier, C. Cachet-Vivier, S. Mezaille, B. L. Wu, C. S. Cha, J-Y. Nedelec, M. Fedoroff, D. Michel, L. T. Yu, Electrochemical Study of Bi2 O 3 and Bi2 O 2 CO 3 by Means of a Cavity Microelectrode. I. Observed Phenomena and Direct Analysis of Results Journal of The Electrochemical Society. ,vol. 147, pp. 4252- 4262 ,(2000) , 10.1149/1.1394049
V. Vivier, C. Cachet-Vivier, C.S. Cha, J.-Y. Nedelec, L.T. Yu, Cavity microelectrode for studying battery materials: application to polyaniline powder Electrochemistry Communications. ,vol. 2, pp. 180- 185 ,(2000) , 10.1016/S1388-2481(00)00004-7
C Delmas, H Cognac-Auradou, JM Cocciantelli, M Ménétrier, JP Doumerc, None, The LixV2O5 system: An overview of the structure modifications induced by the lithium intercalation Solid State Ionics. ,vol. 69, pp. 257- 264 ,(1994) , 10.1016/0167-2738(94)90414-6
V Vivier, A Régis, G Sagon, J.-Y Nedelec, L.T Yu, C Cachet-Vivier, Cyclic voltammetry study of bismuth oxide Bi2O3 powder by means of a cavity microelectrode coupled with Raman microspectrometry Electrochimica Acta. ,vol. 46, pp. 907- 914 ,(2001) , 10.1016/S0013-4686(00)00677-0
J. Lemerle, L. Nejem, J. Lefebvre, Condensation process in polyvanadic acid solutions Journal of Inorganic and Nuclear Chemistry. ,vol. 42, pp. 17- 20 ,(1980) , 10.1016/0022-1902(80)80036-4
Fabrice Coustier, Jason Hill, Boone B. Owens, Stefano Passerini, William H. Smyrl, Doped Vanadium Oxides as Host Materials for Lithium Intercalation Journal of The Electrochemical Society. ,vol. 146, pp. 1355- 1360 ,(1999) , 10.1149/1.1391770
V Vivier, C Cachet‐Vivier, BL Wu, CS Cha, J‐Y Nedelec, LT Yu, CAVITY MICROELECTRODE FOR STUDYING POWDER MATERIALS AT A HIGH POTENTIAL SCAN RATE Electrochemical and Solid State Letters. ,vol. 2, pp. 385- 387 ,(1999) , 10.1149/1.1390845