1,2-Azaborine: The Boron-Nitrogen Derivative of ortho-Benzyne.
作者： Klara Edel , Sarah A. Brough , Ashley N. Lamm , Shih-Yuan Liu , Holger F. Bettinger
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摘要: The BN analogue of ortho-benzyne, 1,2-azaborine, is generated by flash vacuum pyrolysis, trapped under cryogenic conditions, and studied direct spectroscopic techniques. parent aryne spontaneously binds N2 CO2, thus demonstrating its highly reactive nature. interaction with photochemically reversible. CO2 adduct 1,2-azaborine a cyclic carbamate which undergoes photocleavage, resulting in overall splitting.
sci-hub.se 参考文章(50)
Douglas W. Stephan, Frustrated Lewis pairs: from concept to catalysis. Accounts of Chemical Research. ,vol. 48, pp. 306- 316 ,(2015) , 10.1021/AR500375J
Takuji Hatakeyama, Sigma Hashimoto, Tsuyoshi Oba, Masaharu Nakamura, Azaboradibenzo[6]helicene: Carrier Inversion Induced by Helical Homochirality Journal of the American Chemical Society. ,vol. 134, pp. 19600- 19603 ,(2012) , 10.1021/JA310372F
Peter Paetzold, Christoph Von Plotho, Günter Schmid, Roland Boese, Bernhard Schrader, Daniel Bougeard, Uwe Pfeiffer, Rolf Gleiter, Wolfgang Schüfer, Darstellung, Reaktionen und Struktur von tert‐Butyl(tert‐butylimino)boran Chemische Berichte. ,vol. 117, pp. 1089- 1102 ,(1984) , 10.1002/CBER.19841170324
Peter Paetzold, Boron-Nitrogen Analogues of Cyclobutadiene, Benzene and Cyclooctatetraene Phosphorus Sulfur and Silicon and The Related Elements. ,vol. 93, pp. 39- 50 ,(1994) , 10.1080/10426509408021797
Paul J. Fazen, Luke A. Burke, Theoretical Studies of Borazynes and Azaborines Inorganic Chemistry. ,vol. 45, pp. 2494- 2500 ,(2006) , 10.1021/IC051649D
Michael Winkler, Wolfram Sander, Matrix Isolation and Electronic Structure of Di- and Tridehydrobenzenes Australian Journal of Chemistry. ,vol. 63, pp. 1013- 1047 ,(2010) , 10.1071/CH10113
Daniel H. Knack, Jonathan L. Marshall, Gregory P. Harlow, Agnieszka Dudzik, Maciej Szaleniec, Shih-Yuan Liu, Johann Heider, BN/CC‐isosterische Verbindungen als Enzyminhibitoren: Hemmung der Hydroxylierung von Ethylbenzol durch N‐ und B‐Ethyl‐1,2‐azaborin als nichtkonvertierbare Substratanaloga Angewandte Chemie. ,vol. 125, pp. 2660- 2662 ,(2013) , 10.1002/ANGE.201208351
Takuji Hatakeyama, Sigma Hashimoto, Shu Seki, Masaharu Nakamura, Synthesis of BN-fused polycyclic aromatics via tandem intramolecular electrophilic arene borylation. Journal of the American Chemical Society. ,vol. 133, pp. 18614- 18617 ,(2011) , 10.1021/JA208950C
Holger Braunschweig, William C. Ewing, K. Geetharani, Marius Schäfer, Verschiedene Reaktivitäten von Iminoboranen gegenüber Carbenen: BN‐Isostere von Carben‐Alkin‐Addukten Angewandte Chemie. ,vol. 127, pp. 1682- 1685 ,(2015) , 10.1002/ANGE.201409699
Cory A. Jaska, David J. H. Emslie, Michael J. D. Bosdet, Warren E. Piers, Ted S. Sorensen, Masood Parvez, Triphenylene analogues with B2N2C2 cores: synthesis, structure, redox behavior, and photophysical properties. Journal of the American Chemical Society. ,vol. 128, pp. 10885- 10896 ,(2006) , 10.1021/JA063519P