The crystal structures of Ti2O3, a semiconductor, and (Ti0.900V0.100)2O3, a semimetal
作者： William R. Robinson
DOI: 10.1016/0022-4596(74)90082-6
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摘要: Abstract The crystal structures of the semiconductor Ti 2 O 3 and semimetal (Ti 0.900 V 0.100 ) were determined from X-ray diffraction data collected single crystals. compounds are isostructural with Al rhombohedral unit cell dimensions a = 5.4325(8) A α 56.75(1)° for , 5.4692(8) 55.63(1)° doped system. effect substitution +3 is to increase metal-metal distance across shared octahedral face 2.579 in 2.658 while decreasing edge 2.997 2.968 A. metal-oxygen distances exhibit only small changes. These structural changes consistent band theory proposed by Van Zandt, Honig, Goodenough ( 9 explain electrical other properties increasing vanadium content 1− x .
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James A. Ibers, Lonsdale, Kathleen, Dame, John S. Kasper, Gerard D. Rieck, Walter C. Hamilton, Norman Fordyce McKerron Henry, Caroline H. MacGillavry, International tables for X-ray crystallography UT Back-in-Print Service. ,(1962)
L. L. Van Zandt, J. M. Honig, J. B. Goodenough, Resistivity and magnetic order in Ti2O3 Journal of Applied Physics. ,vol. 39, pp. 594- 595 ,(1968) , 10.1063/1.2163536
G.V. Chandrashekhar, Q. Won Choi, J. Moyo, J.M. Honig, The electrical transition in V-doped Ti2O3 Materials Research Bulletin. ,vol. 5, pp. 999- 1007 ,(1970) , 10.1016/0025-5408(70)90048-6
T. C. Chi, R. J. Sladek, Elastic Constants and the Electrical Transition inTi2O3 Physical Review B. ,vol. 7, pp. 5080- 5085 ,(1973) , 10.1103/PHYSREVB.7.5080
S. C. Abrahams, Magnetic and Crystal Structure of Titanium Sesquioxide Physical Review. ,vol. 130, pp. 2230- 2237 ,(1963) , 10.1103/PHYSREV.130.2230
F. J. Morin, Oxides Which Show a Metal-to-Insulator Transition at the Neel Temperature Physical Review Letters. ,vol. 3, pp. 34- 36 ,(1959) , 10.1103/PHYSREVLETT.3.34
A. Mooradian, P. M. Raccah, Raman Study of the Semiconductor-Metal Transition in Ti 2 O 3 Physical Review B. ,vol. 3, pp. 4253- 4256 ,(1971) , 10.1103/PHYSREVB.3.4253
C.N.R. Rao, R.E. Loehman, J.M. Honig, Crystallographic study of the transition in Ti2O3 Physics Letters A. ,vol. 27, pp. 271- 272 ,(1968) , 10.1016/0375-9601(68)90696-8
G. J. Hyland, On the Magnetic Nature of Ti2O3 Physica Status Solidi B-basic Solid State Physics. ,vol. 35, ,(1969) , 10.1002/PSSB.19690350268
W. H. Zachariasen, Multiple diffraction in imperfect crystals Acta Crystallographica. ,vol. 18, pp. 705- 710 ,(1965) , 10.1107/S0365110X65001627