Corundum Structure Oxides Studied by XPS

作者: F Werfel , O Brümmer

DOI: 10.1088/0031-8949/28/1/013

关键词: Electronic structureCorundumSingle crystalMaterials scienceElectronic band structureFermi levelCrystal structureAnalytical chemistryX-ray photoelectron spectroscopySesquioxide

摘要: … The electronic structure behaviour of Me,O, oxides (Me = Ti, V, Cr) has been determined from XPS valence band and core level measurements. From Ti to Cr sesquioxide the relative …

参考文章(21)
D. B. McWhan, J. P. Remeika, Metal-Insulator Transition in (V 1- x Cr x ) 2 O 3 Physical Review B. ,vol. 2, pp. 3734- 3750 ,(1970) , 10.1103/PHYSREVB.2.3734
A. Menth, J. P. Remeika, Magnetic Properties of ( V 1 − x Cr x ) 2 O 3 Physical Review B. ,vol. 2, pp. 3756- 3762 ,(1970) , 10.1103/PHYSREVB.2.3756
Almon G. Turner, Methods in Molecular Orbital Theory ,(1974)
J. Ashkenazi, T. Chuchem, Band structure of V2O3, and Ti2O3 Philosophical Magazine. ,vol. 32, pp. 763- 785 ,(1975) , 10.1080/14786437508221619
N. F. MOTT, Metal-Insulator Transition Reviews of Modern Physics. ,vol. 40, pp. 677- 683 ,(1968) , 10.1103/REVMODPHYS.40.677
J.H. Scofield, Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV Journal of Electron Spectroscopy and Related Phenomena. ,vol. 8, pp. 129- 137 ,(1976) , 10.1016/0368-2048(76)80015-1
S. Lars T. Andersson, ESCA investigation of V2O5+TiO2 catalysts for the vapour phase oxidation of alkylpyridines Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 75, pp. 1356- 1370 ,(1979) , 10.1039/F19797501356
David Adler, Harvey Brooks, THEORY OF SEMICONDUCTOR-TO-METAL TRANSITIONS Physical Review. ,vol. 155, pp. 826- 840 ,(1967) , 10.1103/PHYSREV.155.826
William R. Robinson, The crystal structures of Ti2O3, a semiconductor, and (Ti0.900V0.100)2O3, a semimetal Journal of Solid State Chemistry. ,vol. 9, pp. 255- 260 ,(1974) , 10.1016/0022-4596(74)90082-6
P. D. Dernier, M. Marezio, Crystal Structure of the Low-Temperature Antiferromagnetic Phase of V 2 O 3 Physical Review B. ,vol. 2, pp. 3771- 3776 ,(1970) , 10.1103/PHYSREVB.2.3771