Detailed Investigations into Radical Polymerization Kinetics by Highly Time‐Resolved SP–PLP–EPR
作者： Hendrik Kattner , Michael Buback
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摘要: Summary Instantaneous initiation of radical polymerization by applying an intense laser pulse on a monomer-photoinitiator solution in conjunction with time-resolved detection concentration provides access to detailed picture kinetics. Examples are given measurement chain-length-dependent termination, intramolecular chain transfer as well reversible-deactivation polymerization, namely RAFT and ATRP. The enormous potential the method relates fact that kinetics major acting species, i.e., radicals, may be directly monitored high time resolution.
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