Easy Access to the RAFT Equilibrium Constant
作者： Johannes Barth , Michael Buback , Wibke Meiser , Philipp Vana
DOI: 10.1021/MA902111Z
关键词:
摘要: A method is presented for determination of reliable values the equilibrium constant Keq between propagating radicals (P•) and intermediate (INT•) in reversible addition−fragmentation ch...
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sci-hub.se 参考文章(16)
Robert Rotzoll, Philipp Vana, Synthesis of poly(methyl acrylate) loops grafted onto silica nanoparticles via reversible addition‐fragmentation chain transfer polymerization Journal of Polymer Science Part A. ,vol. 46, pp. 7656- 7666 ,(2008) , 10.1002/POLA.23066
Michelle L. Coote, The kinetics of addition and fragmentation in reversible addition fragmentation chain transfer polymerization: An ab initio study. Journal of Physical Chemistry A. ,vol. 109, pp. 1230- 1239 ,(2005) , 10.1021/JP046131U
Johannes Barth, Michael Buback, Pascal Hesse, Tatiana Sergeeva, Chain-Length-Dependent Termination in n-Butyl Methacrylate and tert-Butyl Methacrylate Bulk Homopolymerizations Studied via SP-PLP-ESR Macromolecules. ,vol. 42, pp. 481- 488 ,(2009) , 10.1021/MA802078G
Tanja Junkers, Alexander Theis, Michael Buback, Thomas P Davis, Martina H Stenzel, Philipp Vana, Christopher Barner-Kowollik, None, Chain length dependent termination in butyl acrylate free-radical polymerization studied via stationary and pulsed laser initiated RAFT polymerization Macromolecules. ,vol. 38, pp. 9497- 9508 ,(2005) , 10.1021/MA051485K
Yungwan Kwak, Atsushi Goto, Takeshi Fukuda, Rate Retardation in Reversible Addition−Fragmentation Chain Transfer (RAFT) Polymerization: Further Evidence for Cross-Termination Producing 3-Arm Star Chain Macromolecules. ,vol. 37, pp. 1219- 1225 ,(2004) , 10.1021/MA030434P
Michael Buback, Pascal Hesse, Tanja Junkers, Tatiana Sergeeva, Thomas Theis, PLP labeling in ESR spectroscopic analysis of secondary and tertiary acrylate propagating radicals Macromolecules. ,vol. 41, pp. 288- 291 ,(2008) , 10.1021/MA702011Q
Yungwan Kwak, Atsushi Goto, Yoshinobu Tsujii, Yasujiro Murata, Koichi Komatsu, Takeshi Fukuda, A Kinetic Study on the Rate Retardation in Radical Polymerization of Styrene with Addition−Fragmentation Chain Transfer Macromolecules. ,vol. 35, pp. 3026- 3029 ,(2002) , 10.1021/MA0118421
Christopher Barner-Kowollik, John F. Quinn, David R. Morsley, Thomas P. Davis, Modeling the reversible addition–fragmentation chain transfer process in cumyl dithiobenzoate‐mediated styrene homopolymerizations: Assessing rate coefficients for the addition–fragmentation equilibrium Journal of Polymer Science Part A. ,vol. 39, pp. 1353- 1365 ,(2001) , 10.1002/POLA.1112
Philipp Vana, Michael Buback, Pascal Hesse, Thomas Junkers, Determination of Addition and Fragmentation Rate Coefficients in RAFT Polymerization via Time‐Resolved ESR Spectroscopy after Laser Pulse Initiation Macromolecular Rapid Communications. ,vol. 27, pp. 182- 187 ,(2006) , 10.1002/MARC.200500716