Methylated flavonols in Larrea cuneifolia

作者: Amalia G. Valesi , E. Rodriguez , G. Vander Velde , T.J. Mabry

DOI: 10.1016/S0031-9422(00)86519-X

关键词:

摘要: Abstract Nine of eleven methylated flavonols isolated from Larrea cuneifolia Cav. collected in Argentina have been fully characterized. UV, MS and NMR spectral data are presented for the nine substances all which were identified as methyl ethers quercetin kaempferol. Two compounds, 7,3′,4′-trimethylquercetin (II) 3,7,3′-trimethylquercetin (III), new natural products. The others 3,7,3′,4′-tetramethylquercetin (I) (retusine), 3,7-dimethylkaempferol (IV), 7,3′-dimethylquercetin (V) (rhamnazin), 3,7-dimethylquercetin (VI) (kumatakenin), 3,3′-dimethylquercetin (VII), 3-methylkaempferol (VIII) 3′-methylquercetin (IX) (isorhamnetin). Nordihydroguaiaretic acid (XII) was also detected.

参考文章(12)
D.G.I. Kingston, Mass spectrometry of organic compounds—VI Tetrahedron. ,vol. 27, pp. 2691- 2700 ,(1971) , 10.1016/S0040-4020(01)98059-7
J.B. Harborne, E. Hall, Plant polyphenols-XIII. Phytochemistry. ,vol. 3, pp. 453- 463 ,(1964) , 10.1016/S0031-9422(00)83630-4
Giovanni Vidari, Paola Vita Finzi, Maria de Bernardi, Flavonols and quinones in stems of aframomum giganteum Phytochemistry. ,vol. 10, pp. 3335- 3339 ,(1971) , 10.1016/S0031-9422(00)97427-2
Andrew Pelter, P. Stainton, M. Barber, The mass spectra of oxygen heterocycles. II. The mass spectra of some flavonoids Journal of Heterocyclic Chemistry. ,vol. 2, pp. 262- 271 ,(1965) , 10.1002/JHET.5570020309
Xorge Domínguez, Rafael Ramírez, Olga Ugaz, Jesús D., Roger Ketcham, Chemical study of the cactus Ariocarpus retusus. Planta Medica. ,vol. 16, pp. 182- 183 ,(1968) , 10.1055/S-0028-1099897
JH Bowie, DW Cameron, Electron impact studies. II. Mass spectra of quercetagetin derivatives Australian Journal of Chemistry. ,vol. 19, pp. 1627- 1635 ,(1966) , 10.1071/CH9661627
Michael G. Barbour, Patterns of Genetic Similarity Between Larrea divaricata of North and South America American Midland Naturalist. ,vol. 81, pp. 54- ,(1969) , 10.2307/2423651