Postsynthetic modification of metal–organic frameworks

摘要: The modification of metal–organic frameworks (MOFs) in a postsynthetic scheme is discussed this critical review. In approach, the MOF assembled and then modified with chemical reagents preservation lattice structure. Recent findings show amide couplings, isocyanate condensations, ‘click’ chemistry, other reactions are suitable for (PSM). addition, number MOFs, from IRMOF-3 to ZIF-90, amenable PSM. generality PSM, both scope range clearly indicates that approach broadly applicable. Indeed, rapid increase reports on PSM demonstrates methodology will play an increasingly important role development MOFs foreseeable future (117 references).