Water effect on the kinetics of 1-pentanol dehydration to di- n -pentyl ether (DNPE) on amberlyst 70
作者： R. Bringué , J. Tejero , M. Iborra , J. F. Izquierdo , C. Fité
DOI: 10.1007/S11244-007-0262-3
关键词:
摘要: Experiments performed at 433 K and 453 with 1-pentanol/water 1-pentanol/DNPE (di-n-pentyl ether) clearly states the inhibiting effect of water released in liquid-phase dehydration 1-pentanol to DNPE on ion-exchange resin. The was described by an empirical correction factor Eley–Rideal rate model deduced a previous work. Best results were obtained including Freundlich-like adsorption isotherm expression. activation energy reaction lowers slightly splitting off effect, it is 114.0 ± 0.1 kJ/mol.
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