REACTANT-PRODUCT DECOUPLING FOR STATE-TO-STATE REACTIVE SCATTERING : FURTHER PARTITIONING IN THE PRODUCT ARRANGEMENTS

摘要: Recently, Peng and Zhang have derived a new time-dependent wavepacket “divide conquer” formalism for decoupling the reactant product pieces of wavepacket. The approach makes it possible to treat initial arrangement dynamics separately while still permitting determination quantitatively accurate S-matrix elements. In this paper we show how procedure can be employed (using suitably defined partitioning potentials) separate various types inelastic scattering within any (or all) arrangements, both in reactions photodissociation.