Electrooxidation of methanol on Pt microparticles dispersed on SnO2 thin films

作者: André L Santos , Demetrius Profeti , Paulo Olivi , None

DOI: 10.1016/J.ELECTACTA.2004.11.006

关键词:

摘要: Abstract In this work, we have prepared electrodes through the electrodeposition of platinum micro particles on SnO 2 thin films in order to verify application system as a catalyst for electrooxidation methanol. The oxide were method polymeric precursor decomposition and calcinated at 550 °C. employed oxides proved be good matrix dispersion since they present high roughness. maximum current was attained content approximately 600 μg cm −2 . chronoamperometric results showed that values obtained methanol up 10 times higher than with platinized under same conditions. possible mechanisms lead enhancement discussed.

参考文章(22)
M. Watanabe, S. Motoo, Electrocatalysis by ad-atoms: Part II. Enhancement of the oxidation of methanol on platinum by ruthenium ad-atoms Journal of Electroanalytical Chemistry. ,vol. 60, pp. 267- 273 ,(1975) , 10.1016/S0022-0728(75)80261-0
Yu Morimoto, Ernest. B. Yeager, CO oxidation on smooth and high area Pt, Pt-Ru and Pt-Sn electrodes Journal of Electroanalytical Chemistry. ,vol. 441, pp. 77- 81 ,(1998) , 10.1016/S0022-0728(97)00312-4
Yu Morimoto, Ernest B Yeager, Comparison of methanol oxidations on Pt, Pt|Ru and Pt|Sn electrodes Journal of Electroanalytical Chemistry. ,vol. 444, pp. 95- 100 ,(1998) , 10.1016/S0022-0728(97)00563-9
Pawel J Kulesza, Monika Matczak, Anna Wolkiewicz, Bozena Grzybowska, Mariusz Galkowski, Marcin A Malik, Andrzej Wieckowski, Electrocatalytic properties of conducting polymer based composite film containing dispersed platinum microparticles towards oxidation of methanol Electrochimica Acta. ,vol. 44, pp. 2131- 2137 ,(1999) , 10.1016/S0013-4686(98)00321-1
A.A Mikhaylova, E.B Molodkina, O.A Khazova, V.S Bagotzky, Electrocatalytic and adsorption properties of platinum microparticles electrodeposited into polyaniline films Journal of Electroanalytical Chemistry. ,vol. 509, pp. 119- 127 ,(2001) , 10.1016/S0022-0728(01)00479-X
Wolf Vielstich, Electrochemical energy conversion: methanol fuel cell as example Journal of the Brazilian Chemical Society. ,vol. 14, pp. 503- 509 ,(2003) , 10.1590/S0103-50532003000400003
L. Dubau, F. Hahn, C. Coutanceau, J.-M. Léger, C. Lamy, On the structure effects of bimetallic PtRu electrocatalysts towards methanol oxidation Journal of Electroanalytical Chemistry. ,vol. 554, pp. 407- 415 ,(2003) , 10.1016/S0022-0728(03)00308-5
T Iwasita, Electrocatalysis of methanol oxidation Electrochimica Acta. ,vol. 47, pp. 3663- 3674 ,(2002) , 10.1016/S0013-4686(02)00336-5