The rate coefficient for the reaction of O(3P= with CH3OOH at 297 K

摘要: The absolute second-order rate coefficient for the reaction, O( 3 P) + CH OOH → products, was measured to be k 1 = (1.06 ± 0.26) × 10 −14 cm molec −1 s at 297 K, where quoted error is 2σ including precision and estimated systematic errors. possible presence of (CH 2 ) O in our sample leads a large which reflects relatively uncertainty indicated. generated excess by photolyzing small amount 532 nm, does not photolyze. removal experiments monitored resonance fluorescence detection. increased reactivity with relative H interpreted as due abstraction from group