d-Pinitol Solubility in Supercritical CO2: Experimental Data and Correlation

作者: Amparo Cháfer , Tiziana Fornari , Roumiana P. Stateva , Angel Berna

DOI: 10.1021/JE0504257

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摘要: Measurements of d-pinitol solubility in supercritical CO2 the temperature range (313 to 333) K and pressures ranging from 10 40 MPa are reported for first time this work. Two different thermodynamic models applied correlate experimental solubilities:  a cubic-type equation state (the Soave−Redlich−Kong, SRK) model based on group contribution approach Group Contribution Equation State, GC-EoS). Both demonstrate high capability describe solid−gas-phase equilibria system. In addition, values thermophysical properties, sublimation pressure, solid molar volume also given.

参考文章(17)
C. J. Bailey, S. L. Turner, Glucosamine‐induced insulin resistance in L6 muscle cells Diabetes, Obesity and Metabolism. ,vol. 6, pp. 293- 298 ,(2004) , 10.1111/J.1462-8902.2004.00350.X
Georgi St. Cholakov, William A Wakeham, Roumiana P Stateva, Estimation of normal boiling points of hydrocarbons from descriptors of molecular structure Fluid Phase Equilibria. ,vol. 163, pp. 21- 42 ,(1999) , 10.1016/S0378-3812(99)00207-1
J -I Kim, J C Kim, M -J Kang, M -S Lee, J -J Kim, I -J Cha, Effects of pinitol isolated from soybeans on glycaemic control and cardiovascular risk factors in Korean patients with type II diabetes mellitus: a randomized controlled study. European Journal of Clinical Nutrition. ,vol. 59, pp. 456- 458 ,(2005) , 10.1038/SJ.EJCN.1602081
A Berna, A Cháfer, J.B Montón, High-pressure solubility data of the system resveratrol (3)+ethanol (2)+CO2 (1) The Journal of Supercritical Fluids. ,vol. 19, pp. 133- 139 ,(2001) , 10.1016/S0896-8446(00)00088-7
R.K. Singh, B.L. Pandey, M. Tripathi, V.B. Pandey, Anti-inflammatory effect of (+)-pinitol Fitoterapia. ,vol. 72, pp. 168- 170 ,(2001) , 10.1016/S0367-326X(00)00267-7
Sarah H Bates, Robert B Jones, Clifford J Bailey, Insulin-like effect of pinitol British Journal of Pharmacology. ,vol. 130, pp. 1944- 1948 ,(2000) , 10.1038/SJ.BJP.0703523
A Berna, A Cháfer, J.B Montón, S Subirats, High-pressure solubility data of system ethanol (1)+catechin (2)+CO2 (3) The Journal of Supercritical Fluids. ,vol. 20, pp. 157- 162 ,(2001) , 10.1016/S0896-8446(01)00063-8
Tiziana Fornari, Amparo Chafer, Roumiana P. Stateva, Guillermo Reglero, A New Development in the Application of the Group Contribution Associating Equation of State To Model Solid Solubilities of Phenolic Compounds in SC−CO2 Industrial & Engineering Chemistry Research. ,vol. 44, pp. 8147- 8156 ,(2005) , 10.1021/IE050443H
William A. Wakeham, Georgi St. Cholakov, Roumiana P. Stateva, Liquid Density and Critical Properties of Hydrocarbons Estimated from Molecular Structure Journal of Chemical & Engineering Data. ,vol. 47, pp. 559- 570 ,(2002) , 10.1021/JE010308L