Transition Metal Carbene Complexes
作者： E.O. Fischer , M.D. Cooke
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摘要: By using an optically active metal-carbene complex we were able to isolate cyclopropane from the reaction of diethyl fumarate with [(−) (R)-methylphenylpropylphosphine] (phenylmethoxycarbene) tetracarbonylchromium. In addition being synthetically useful for preparation cyclopropanes optical activity, this demonstrates that no free carbene is involved in mechanism reaction.
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openlibrary.org参考文章(8)
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