Selective cis-chlorination of olefins by antimony(V) chloride

作者: Sakae Uemura , Osamu Sasaki , Masaya Okano

DOI: 10.1039/C29710001064

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摘要: Treatment of olefins with SbCl5 in CCl4 gave cis-vic-dichloroalkanes predominantly; e.g. cis- and trans-but-2-enes cyclohexene meso- (±)-2,3-dichlorobutanes cis-1,2-dichlorocyclohexane respectively.

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