Meso-Tetraarylporphyrins Bearing Nitro or Amino Groups: Synthetic Strategies and Reactivity Profiles

作者: Vanda I. Vaz Serra , Sónia M. G. Pires , Cristina M. A. Alonso , Maria G. P. M. S. Neves , Augusto C. Tomé

DOI: 10.1007/7081_2013_101

关键词:

摘要: Porphyrins bearing nitro and amino substituents have been used as excellent synthons for further functionalization in order to obtain new compounds with adequate features a wide range of applications. This chapter brings an update on the effort several research groups study synthesis reactivity meso-tetraarylporphyrins those functionalities.

参考文章(143)
Joana I.T. Costa, Augusto C. Tomé, Maria G.P.M.S. Neves, José A.S. Cavaleiro, 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin: a versatile platform to novel porphyrinic materials Journal of Porphyrins and Phthalocyanines. ,vol. 15, pp. 1116- 1133 ,(2011) , 10.1142/S1088424611004294
William J. Kruper, Thomas A. Chamberlin, Monica Kochanny, Regiospecific aryl nitration of meso-substituted tetraarylporphyrins: a simple route to bifunctional porphyrins Journal of Organic Chemistry. ,vol. 54, pp. 2753- 2756 ,(1989) , 10.1021/JO00272A057
James P. Collman, Robert R. Gagne, Christopher Reed, Thomas R. Halbert, George Lang, Ward T. Robinson, Picket fence porphyrins. Synthetic models for oxygen binding hemoproteins Journal of the American Chemical Society. ,vol. 97, pp. 1427- 1439 ,(1975) , 10.1021/JA00839A026
Qimao Huang, Zhiquan Pan, Ping Wang, Zhangping Chen, Xiaolian Zhang, Hansheng Xu, Zinc(II) and copper(II) complexes of β-substituted hydroxylporphyrins as tumor photosensitizers Bioorganic & Medicinal Chemistry Letters. ,vol. 16, pp. 3030- 3033 ,(2006) , 10.1016/J.BMCL.2005.02.094
Henry J. Callot, Sébastien Richeter, Christophe Jeandon, Christian Sauber, Jean-Paul Gisselbrecht, Romain Ruppert, Preparation, mass spectrometry and electrochemical studies of metal connected porphyrin oligomers Journal of Porphyrins and Phthalocyanines. ,vol. 06, pp. 423- 430 ,(2002) , 10.1142/S108842460200052X
Asha Brown, Paul D. Beer, Porphyrin-functionalised rotaxanes for anion recognition Dalton Transactions. ,vol. 41, pp. 118- 129 ,(2012) , 10.1039/C1DT11372K
David P. Cormode, Michael G. B. Drew, Raymond Jagessar, Paul D. Beer, Metalloporphyrin anion sensors: the effect of the metal centre on the anion binding properties of amide-functionalised and tetraphenyl metalloporphyrins. Dalton Transactions. pp. 6732- 6741 ,(2008) , 10.1039/B807153E
Raymond Luguya, Laurent Jaquinod, Frank R Fronczek, M.Graça H Vicente, Kevin M Smith, Synthesis and reactions of meso-(p-nitrophenyl)porphyrins Tetrahedron. ,vol. 60, pp. 2757- 2763 ,(2004) , 10.1016/J.TET.2004.01.080
Maxwell J. Crossley, Lionel G. King, Novel heterocyclic systems from selective oxidation at the β-pyrrolic position of porphyrins Journal of The Chemical Society, Chemical Communications. pp. 920- 922 ,(1984) , 10.1039/C39840000920
Ana T.P.C. Gomes, Filipe A. Almeida Paz, Maria G.P.M.S. Neves, Augusto C. Tomé, Artur M.S. Silva, Maria Cecília B.V. de Souza, Vítor F. Ferreira, José A.S. Cavaleiro, Catalytic carbene insertion into an aminoporphyrin and formation of a new chiral supramolecular porphyrin system Tetrahedron Letters. ,vol. 52, pp. 4741- 4744 ,(2011) , 10.1016/J.TETLET.2011.06.120