Catalytic carbene insertion into an aminoporphyrin and formation of a new chiral supramolecular porphyrin system
作者： Ana T.P.C. Gomes , Filipe A. Almeida Paz , Maria G.P.M.S. Neves , Augusto C. Tomé , Artur M.S. Silva
DOI: 10.1016/J.TETLET.2011.06.120
关键词: Stereochemistry 、 Chemistry 、 Ethyl diazoacetate 、 Rhodium 、 Substituent 、 Porphyrin 、 Carbene 、 Supramolecular chemistry 、 Catalysis 、 Polymer chemistry 、 Insertion reaction
摘要: Abstract The catalytic insertion of ethyl diazoacetate into a porphyrin derivative bearing an NH2 substituent, in the presence Rh-based catalyst, was investigated. X-ray analysis one isolated products reveals formation chiral supramolecular system.
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