A New Insight into the Catalytic Decomposition of Ethyl Diazoacetate in the Presence of meso-Tetraarylporphyrin (=5,10,15,20-Tetraaryl-21H,23H-porphine) Complexes
作者： Ana T. P. C. Gomes , Raquel A. C. Leão , Cristina M. A. Alonso , Maria G. P. M. S. Neves , Maria A. F. Faustino
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摘要: The decomposition of ethyl diazoacetate by several catalysts in the presence meso-tetraarylporphyrin complexes with different electronic features was evaluated. distribution obtained products (chlorins, bacteriochlorins, isobacteriochlorins, and porphyrin derivatives resulting from CH insertion Buchner ring expansion) is dependent on catalyst meso-aryl groups.
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