Redox molecular sieve catalysts for the aerobic selective oxidation of hydrocarbons
作者： John Meurig Thomas , Robert Raja , Gopinathan Sankar , Robert G Bell
DOI: 10.1016/S0167-2991(00)81071-X
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摘要: We report the design and performance of redox molecular sieve catalysts, containing isolated, four-coordinated transition metal ions that are substitutionally incorporated into framework act, in concert with surrounding structure, as shape-selective regiospecific catalysts for oxidation linear cyclic alkanes, using oxygen oxidant. These materials have also proved effective Baeyer-Villiger ketones to lactones alkenes epoxides, a sacrificial aldehyde air an
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