Atomic Disorder in Fossil Tooth and Bone Mineral: An FTIR Study Using the Grinding Curve Method

作者: Y. Asscher , L. Regev , S. Weiner , E. Boaretto

DOI: 10.4000/ARCHEOSCIENCES.3062

关键词:

摘要: Bone and tooth mineral generally undergo diagenetic changes. These changes in the carbonate hydroxyapatite structure composition can affect signals embedded phase, such as migration behavior, age of specimen reconstruction past environments. Mineral preservation state be assessed using infrared spectroscopy which provides information on crystal disorder at atomic level composition. Here we present a new approach to evaluate standard KBr sample mounting method. We show that by repeated grinding then plotting splitting factor against width major phosphate absorption peak after each grinding, curves with well defined trend lines obtained. The offsets between reflect differences disorder. curve used bone, dentine enamel mineral.

参考文章(13)
Boaz Luz, Yehoshua Kolodny, Michal Horowitz, Fractionation of oxygen isotopes between mammalian bone-phosphate and environmental drinking water Geochimica et Cosmochimica Acta. ,vol. 48, pp. 1689- 1693 ,(1984) , 10.1016/0016-7037(84)90338-7
Kristin M Poduska, Lior Regev, Elisabetta Boaretto, Lia Addadi, Steve Weiner, Leeor Kronik, Stefano Curtarolo, None, Decoupling Local Disorder and Optical Effects in Infrared Spectra: Differentiating Between Calcites with Different Origins Advanced Materials. ,vol. 23, pp. 550- 554 ,(2011) , 10.1002/ADMA.201003890
E.D. Eanes, A.H. Reddi, The effect of fluoride on bone mineral apatite Metabolic Bone Disease and Related Research. ,vol. 2, pp. 3- 10 ,(1979) , 10.1016/0221-8747(79)90012-2
JOHN D. TERMINE, AARON S. POSNER, Infra-Red Determination of the Percentage of Crystallinity in Apatitic Calcium Phosphates Nature. ,vol. 211, pp. 268- 270 ,(1966) , 10.1038/211268A0
Yotam Asscher, Steve Weiner, Elisabetta Boaretto, Variations in Atomic Disorder in Biogenic Carbonate Hydroxyapatite Using the Infrared Spectrum Grinding Curve Method Advanced Functional Materials. ,vol. 21, pp. 3308- 3313 ,(2011) , 10.1002/ADFM.201100266
Eva M. Wild, Maria Teschler-Nicola, Walter Kutschera, Peter Steier, Erik Trinkaus, Wolfgang Wanek, Direct dating of Early Upper Palaeolithic human remains from Mladeč Nature. ,vol. 435, pp. 332- 335 ,(2005) , 10.1038/NATURE03585
Stephen Weiner, Ofer Bar-Yosef, None, States of preservation of bones from prehistoric sites in the Near East: A survey Journal of Archaeological Science. ,vol. 17, pp. 187- 196 ,(1990) , 10.1016/0305-4403(90)90058-D
G.M. Milton, S.J. Kramer, T.G. Kotzer, J.C.D. Milton, H.R. Andrews, L.A. Chant, R.J. Cornett, W.G. Davies, B.F. Greiner, Y. Imahori, V.T. Koslowsky, J.W. McKay, Cl 36 — A potential paleodating tool Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 123, pp. 371- 377 ,(1997) , 10.1016/S0168-583X(96)00748-3