The coupling of methylene and vinyl ligands at a ruthenium(II) centre
作者： Anthony F. Hill , Chean T. Ho , James D. E. T. Wilton-Ely
DOI: 10.1039/A704157H
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摘要: The reaction of [Ru(CHCH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η3-CH2CHCH2)Cl(CO)(PPh3)2] which is also product reactions [RuHCl(CO)(PPh3)3] either allene or propyne and reacts subsequently NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] allene.
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