Dynamical relaxation of H2(v,j) on a copper surface

作者: Mario Cacciatore , Gert Due Billing

DOI: 10.1016/0039-6028(90)90585-V

关键词:

摘要: Abstract Dynamical studies of hydrogen-copper collisions are carried out using an analytical potential energy surface fitted to the data recent ab initio calculations. We have investigated role tunnelling as well importance electron-hole pair excitation and particularly effect screening in between hydrogen molecule copper surface.

参考文章(32)
Ger Due Billing, Mario Cacciatore, Semiclassical calculation of the probability for formation of CO2 on a Pt(111) surface Chemical Physics. ,vol. 103, pp. 137- 150 ,(1986) , 10.1016/0301-0104(86)85109-6
G. D. Kubiak, G. O. Sitz, R. N. Zare, Recombinative desorption dynamics: Molecular hydrogen from Cu(110) and Cu(111) Journal of Chemical Physics. ,vol. 83, pp. 2538- 2551 ,(1985) , 10.1063/1.449300
B. Hellsing, M. Persson, B.I. Lundqvist, Electronic damping mechanism for vibrations, rotations, and translations of adsorbates on metal surfaces Surface Science. ,vol. 126, pp. 147- 153 ,(1983) , 10.1016/0039-6028(83)90703-3
Zvi Kirson, R.B. Gerber, A. Nitzan, Excitation and emission of metal electrons in atom-surface collisions Surface Science. ,vol. 124, pp. 279- 296 ,(1983) , 10.1016/0039-6028(83)90350-3
P. Madhavan, J. L. Whitten, Theoretical studies of the chemisorption of hydrogen on copper The Journal of Chemical Physics. ,vol. 77, pp. 2673- 2683 ,(1982) , 10.1063/1.444094
Gregory E. Korzeniewski, Eric Hood, Horia Metiu, The role of electron-hole pair excitations in desorption dynamics Journal of Chemical Physics. ,vol. 80, pp. 6274- 6284 ,(1984) , 10.1063/1.446730
Takao Kwan, Rate of Hydrogen Adsorption on Reduced Copper Bulletin of the Chemical Society of Japan. ,vol. 23, pp. 73- 75 ,(1950) , 10.1246/BCSJ.23.73
Hiromu Ueba, Vibrational state of the chemisorbed molecule on metal surfaces: Role of electron‐hole pair excitation The Journal of Chemical Physics. ,vol. 77, pp. 3759- 3766 ,(1982) , 10.1063/1.444242