The pentanuclear FeII cluster [(C5H4)6Fe5]2−: bringing together ferrocene sandwiches and homoleptic FeII-cyclopentadienyl σ-complexes
作者： Ingeborg Sänger , Julia B. Heilmann , Michael Bolte , Hans-Wolfram Lerner , Matthias Wagner
DOI: 10.1039/B602359B
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摘要: Reaction of [(fc)3(Li)6·(TMEDA)2] with FeCl2 gives the pentanuclear iron complex [(fc)3(Fe)2(Li)2·(TMEDA)2] featuring two ferra[1]ferrocenophane moieties bridged by a 1,1′-ferrocenediyl unit; non-ferrocene FeII ions are tetra-coordinate and adopt high-spin state.
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