Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers
作者： Holger Braunschweig , Maria Friedrich , Thomas Kupfer , Krzysztof Radacki
DOI: 10.1039/C1CC10207A
关键词:
摘要: [1]Zirconametalloarenophanes [Cr(η5-C5H4)ZrCp′2(η7-C7H6)] and [Mn(η5-C5H4)ZrCp′2(η6-C6H5)] (Cp′ = C5H4tBu) have been isolated for the first time. These species represent potential precursors en route to metal-enriched metallopolymers by ROP. The electronic structure was assessed means of UV-visible spectroscopy TD-DFT calculations.
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