Dielectric and conductivity spectra of polyethylene oxide complexes of sodium salt

作者: T. Wong , M. Brodwin , B.L. Papke , D.F. Shriver

DOI: 10.1016/0167-2738(81)90347-7

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摘要: Abstract Dynamics of PEO·NaSCN (a solid electrolyte) and PEO·NaBH 4 (an insulator) have been studied by dielectric loss measurements in the radio microwave frequency regions. Above 10 GHz, response is principally attributed to contributions from vibrational motions polymer itself. The mid NaSCN complex indicates a coupling between sodium ion chain. absence extra low polarization NaBH suggest that held tightly backbone,,possibly due ion-pairing with anion.

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