A kinetic model for the methanol-higher alcohol synthesis from CO/CO2/H2 over Cu/ZnO-based catalysts including simultaneous formation of methyl esters and hydrocarbons

作者: B.B. Breman , A.C.C.M. Beenackers , E. Oesterholt

DOI: 10.1016/S0009-2509(05)80030-2

关键词:

摘要: … Notice that, also for L' = L, which implies one reaction mechanism for linear chain growth only, the parameter L' only equals L if the contribution of the CO2/H2 route to the overall …

参考文章(19)
Kevin J. Smith, Chyi Woei Young, Richard G. Herman, Kamil Klier, Development of a kinetic model for alcohol synthesis over a cesium-promoted copper/zinc oxide catalyst Industrial & Engineering Chemistry Research. ,vol. 30, pp. 61- 71 ,(1991) , 10.1021/IE00049A010
M. S. Bartlett, Properties of Sufficiency and Statistical Tests Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 160, pp. 268- 282 ,(1992) , 10.1007/978-1-4612-0919-5_8
D.J. Elliott, Filippo Pennella, Mechanism of ethanol formation from synthesis gas over CuO/ZnO/Al2O3 Journal of Catalysis. ,vol. 114, pp. 90- 99 ,(1988) , 10.1016/0021-9517(88)90011-5
Kevin J. Smith, Robert B. Anderson, The higher alcohol synthesis over promoted Cu/ZnO catalysts Canadian Journal of Chemical Engineering. ,vol. 61, pp. 40- 45 ,(1983) , 10.1002/CJCE.5450610106
John G Nunan, Charles E Bogdan, Kamil Klier, Kevin J Smith, Chyi-Woei Young, Richard G Herman, Methanol and C2 oxygenate synthesis over cesium doped Cu/ZnO and Cu/ZnO/Al2O3 catalysts: A study of selectivity and 13C incorporation patterns Journal of Catalysis. ,vol. 113, pp. 410- 433 ,(1988) , 10.1016/0021-9517(88)90268-0
G.H. Graaf, J.G.M. Winkelman, E.J. Stamhuis, A.A.C.M. Beenackers, Kinetics of the three phase methanol synthesis Chemical Engineering Science. ,vol. 43, pp. 2161- 2168 ,(1988) , 10.1016/0009-2509(88)87098-2
John G Nunan, Charles E Bogdan, Kamil Klier, Kevin J Smith, Chyi-Woei Young, Richard G Herman, Higher alcohol and oxygenate synthesis over cesium-doped Cu/Zno catalysts Journal of Catalysis. ,vol. 116, pp. 195- 221 ,(1989) , 10.1016/0021-9517(89)90086-9
J.C. Slaa, J.G. van Ommen, J.R.H. Ross, The synthesis of higher alcohols using modified Cu/ZnO/Al2O3 catalysts Catalysis Today. ,vol. 15, pp. 129- 148 ,(1992) , 10.1016/0920-5861(92)80125-7
Kevin J Smith, Robert B Anderson, A chain growth scheme for the higher alcohols synthesis Journal of Catalysis. ,vol. 85, pp. 428- 436 ,(1984) , 10.1016/0021-9517(84)90232-X
J.C.J. Bart, R.P.A. Sneeden, Copper-Zinc Oxide-Alumina Methanol Catalysts Revisited Catalysis Today. ,vol. 2, pp. 1- 124 ,(1987) , 10.1016/0920-5861(87)80001-9