Study on the Synthesis, Photophysical Properties and Singlet Oxygen Generation Behavior of Bodipy-Functionalized Cyclotriphosphazenes.
作者： Elif Şenkuytu , Zeynep Cebesoy , Gönül Yenilmez Çiftçi , Esra Tanrıverdi Eçik
DOI: 10.1007/S10895-016-1987-9
关键词:
摘要: A new series of bodipy-functionalized cyclotriphosphazene derivatives were designed and synthesized. The identities all newly synthesized compounds confirmed by using 1H, 13C, 31P NMR spectroscopies. photophysical properties cyclotriphosphazenes investigated via absorption fluorescense spectroscopies in dichloromethane. Singlet oxygen generation capacities also examined the trap molecule 1,3-diphenylisobenzofuran. targeted showed high molar extinction coefficients NIR region respectable singlet quantum yields when compared to that methylene blue. are efficient photosensitizers be potentially used for generation.
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sci-hub.se 参考文章(32)
Anyanee Kamkaew, Siang Hui Lim, Hong Boon Lee, Lik Voon Kiew, Lip Yong Chung, Kevin Burgess, BODIPY dyes in photodynamic therapy. Chemical Society Reviews. ,vol. 42, pp. 77- 88 ,(2013) , 10.1039/C2CS35216H
Jonathan F. Lovell, Tracy W. B. Liu, Juan Chen, Gang Zheng, Activatable photosensitizers for imaging and therapy Chemical Reviews. ,vol. 110, pp. 2839- 2857 ,(2010) , 10.1021/CR900236H
Tuba Yıldırım, Kemal Bilgin, Gönül Yenilmez Çiftçi, Esra Tanrıverdi Eçik, Elif Şenkuytu, Yıldız Uludağ, Leman Tomak, Adem Kılıç, Synthesis, cytotoxicity and apoptosis of cyclotriphosphazene compounds as anti-cancer agents. European Journal of Medicinal Chemistry. ,vol. 52, pp. 213- 220 ,(2012) , 10.1016/J.EJMECH.2012.03.018
Takatoshi Yogo, Yasuteru Urano, Yukiko Ishitsuka, Fumio Maniwa, Tetsuo Nagano, Highly efficient and photostable photosensitizer based on BODIPY chromophore. Journal of the American Chemical Society. ,vol. 127, pp. 12162- 12163 ,(2005) , 10.1021/JA0528533
Gönül Yenilmez Çiftçi, Elif Şenkuytu, Mahmut Durmuş, Fatma Yuksel, Adem Kılıç, Fluorenylidene bridged cyclotriphosphazenes: ‘turn-off’ fluorescence probe for Cu2+ and Fe3+ ions Dalton Transactions. ,vol. 42, pp. 14916- 14926 ,(2013) , 10.1039/C3DT51426A
Vadapalli Chandrasekhar, Selvarajan Nagendran, Phosphazenes as scaffolds for the construction of multi-site coordination ligands Chemical Society Reviews. ,vol. 30, pp. 193- 203 ,(2001) , 10.1039/B004872K
Jianzhang Zhao, Kejing Xu, Wenbo Yang, Zhijia Wang, Fangfang Zhong, The triplet excited state of Bodipy: formation, modulation and application Chemical Society Reviews. ,vol. 44, pp. 8904- 8939 ,(2015) , 10.1039/C5CS00364D
M. Rajeswara Rao, G. Gayatri, Amit Kumar, G. Narahari Sastry, M. Ravikanth, Cyclotriphosphazene Ring as a Platform for Multiporphyrin Assemblies Chemistry: A European Journal. ,vol. 15, pp. 3488- 3496 ,(2009) , 10.1002/CHEM.200802413
Heechan Kim, Wooyul Kim, Yuri Mackeyev, Gi-Seon Lee, Hee-Joon Kim, Takashi Tachikawa, Seokwon Hong, Sanghyup Lee, Jungbae Kim, Lon J. Wilson, Tetsuro Majima, Pedro J. J. Alvarez, Wonyong Choi, Jaesang Lee, Selective Oxidative Degradation of Organic Pollutants by Singlet Oxygen-Mediated Photosensitization: Tin Porphyrin versus C60 Aminofullerene Systems Environmental Science & Technology. ,vol. 46, pp. 9606- 9613 ,(2012) , 10.1021/ES301775K
Raymond Bonnett, Photosensitizers of the porphyrin and phthalocyanine series for photodynamic therapy Chemical Society Reviews. ,vol. 24, pp. 19- 33 ,(1995) , 10.1039/CS9952400019