Synthesis, Characterization, Electrochemistry, and Spectroscopic Properties of Some Anthracenyl Functionalized Phthalocyanine Complexes of Ruthenium(II)
作者： Adewale O. Adeloye , Peter A. Ajibade
DOI: 10.1155/2014/257206
关键词:
摘要: The synthesis of single- and double-decked anthracenyl functionalized ruthenium(II) phthalocyanine complexes has been achieved through a controlled electrophilic aromatic substitution reaction the free unsubstituted with preformed 9-bromo-10-(2,3-dimethylacrylic acid)-anthracene and/or acid)-dianthracene using 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as catalyst. were characterized by IR, UV-Vis, fluorescence, 1H, 13C NMR, elemental analyses. A dimeric complex (, where is 9-dianthracenyl-10-(2,3-dimethylacrylic acid), obtained major product dianthracenyl-substituted ruthenium displays strong near-infrared visible absorption band wavelength maxima at 1027 nm ( M−1 cm−1), an interesting photoluminescent electroredox active properties.
hindawi.com参考文章(31)
O. V. Shishkina, V. E. Maizlish, G. P. Shaposhnikov, Nucleophilic Substitution in 4-Bromo-5-nitrophthalodinitrile: IV. 5-Nitro-4-(phenylthio)phthalodinitrile and Octa-substituted Metal Phthalocyanines Based Thereon Russian Journal of General Chemistry. ,vol. 71, pp. 243- 245 ,(2001) , 10.1023/A:1012351405780
Neil B. McKeown, Phthalocyanine Materials: Synthesis, Structure and Function ,(1998)
Md. K. Nazeeruddin, R. Humphry-Baker, M. Grätzel, Md. K. Nazeeruddin, R. Humphry-Baker, M. Grätzel, Barry A. Murrer, Efficient near IR sensitization of nanocrystalline TiO2 films by ruthenium phthalocyanines Chemical Communications. pp. 719- 720 ,(1998) , 10.1039/A708834E
Tristan Rawling, Andrew McDonagh, Ruthenium phthalocyanine and naphthalocyanine complexes: Synthesis, properties and applications Coordination Chemistry Reviews. ,vol. 251, pp. 1128- 1157 ,(2007) , 10.1016/J.CCR.2006.09.011
Wolfram Kobel, Michael Hanack, Bis axially coordinated (phthalocyaninato)ruthenium(II) compounds Inorganic Chemistry. ,vol. 25, pp. 103- 107 ,(1986) , 10.1021/IC00221A027
Adewale O. Adeloye, Peter A. Ajibade, Synthesis and Characterization of a Heteroleptic Ru(II) Complex of Phenanthroline Containing Oligo-Anthracenyl Carboxylic Acid Moieties International Journal of Molecular Sciences. ,vol. 11, pp. 3158- 3176 ,(2010) , 10.3390/IJMS11093158
A. Capobianchi, A. M. Paoletti, G. Pennesi, G. Rossi, R. Caminiti, C. Ercolani, Ruthenium Phthalocyanine: Structure, Magnetism, Electrical Conductivity Properties, and Role in Dioxygen Activation and Oxygen Atom Transfer to 1-Octene Inorganic Chemistry. ,vol. 33, pp. 4635- 4640 ,(1994) , 10.1021/IC00099A013
Nicolas Godbert, Martin R. Bryce, Slimane Dahaoui, Andrei S. Batsanov, Judith A. K. Howard, Paul Hazendonk, Hydroxymethyl‐Functionalised 9,10‐Bis(1,3‐dithiol‐2‐ylidene)‐9,10‐Dihydroanthracene π‐Electron Donors as Synthetic Intermediates for Supramolecular Structures European Journal of Organic Chemistry. ,vol. 2001, pp. 749- 757 ,(2001) , 10.1002/1099-0690(200102)2001:4<749::AID-EJOC749>3.0.CO;2-V
Takamitsu Fukuda, Terumi Ishiguro, Nagao Kobayashi, Non-planar phthalocyanines with Q-bands beyond 800nm Tetrahedron Letters. ,vol. 46, pp. 2907- 2909 ,(2005) , 10.1016/J.TETLET.2005.02.134
Adewale O. Adeloye, Peter A. Ajibade, Synthesis and characterization of a Ru(II) complex with functionalized phenanthroline ligands having single-double linked anthracenyl and 1-methoxy-1-buten-3-yne moieties. Molecules. ,vol. 15, pp. 7570- 7581 ,(2010) , 10.3390/MOLECULES15117570