Study of metal fractionation in river sediments. A comparison between kinetic and sequential extraction procedures.

作者: M Jesús Gismera , Javier Lacal , Pilar da Silva , Rosario Garcı́a , M Teresa Sevilla

DOI: 10.1016/J.ENVPOL.2003.08.004

关键词:

摘要: The extraction kinetic of trace metals (Cd, Cu, Pb, and Zn) in river sediments by four agents was studied. As extractants ammonium acetate, acetic acid, hydroxylamine EDTA solutions were assayed. These reagents can leach the more or less selectively from several metal compartments sediments. leaching model permits classification species labile moderately-labile ones. combination two non specific a high characterisation distribution leachability. results obtained with this compared data SM&T sequential procedure, order to characterise chemical nature leached metal.

参考文章(17)
C. M. Davidson, A. M. Ure, Chemical speciation in the environment ,(1994)
M.Mar Ortiz Viana, M.Pilar da Silva, Raquel Agraz, Jesús R. Procopio, M.Teresa Sevilla, Lucas Hernandez, Comparison of two kinetic approaches for copper speciation using ion-exchange columns and ion-exchange modified carbon paste electrodes Analytica Chimica Acta. ,vol. 382, pp. 179- 188 ,(1999) , 10.1016/S0003-2670(98)00786-7
Christine Gleyzes, Sylvaine Tellier, Michel Astruc, Fractionation studies of trace elements in contaminated soils and sediments: a review of sequential extraction procedures Trends in Analytical Chemistry. ,vol. 21, pp. 451- 467 ,(2002) , 10.1016/S0165-9936(02)00603-9
Ph. Quevauviller, H.A. van der Sloot, A. Ure, H. Muntau, A. Gomez, G. Rauret, Conclusions of the workshop: harmonization of leaching/extraction tests for environmental risk assessment Science of The Total Environment. ,vol. 178, pp. 133- 139 ,(1996) , 10.1016/0048-9697(95)04805-7
O Schramel, B Michalke, A Kettrup, Study of the copper distribution in contaminated soils of hop fields by single and sequential extraction procedures Science of The Total Environment. ,vol. 263, pp. 11- 22 ,(2000) , 10.1016/S0048-9697(00)00606-9
William F. Pickering, Larry M. Shuman, Selective Chemical Extraction of Soil Components and Bound Metal Species Critical Reviews in Analytical Chemistry. ,vol. 12, pp. 233- 266 ,(1981) , 10.1080/10408348108542747