Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu3−xPdx(BTC)2]n
作者： Wenhua Zhang , Zhihao Chen , Majd Al-Naji , Penghu Guo , Stefan Cwik
DOI: 10.1039/C6DT02893D
关键词:
摘要: Simultaneous incorporation of palladium within Pd–Pd and/or Pd–Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, framework substitution Cu2+ by Pd2+ well pore loading with PdNPs confirmed characterized XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in aqueous-phase hydrogenation p-nitrophenol (PNP) NaBH4 to p-aminophenol (PAP).
rsc.org
mpg.de
sci-hub.se 参考文章(56)
Xiaoqian Jia, Shihua Wang, Yu Fan, A novel strategy for producing highly dispersed Pd particles on ZIF-8 through the occupation and unoccupation of carboxyl groups and its application in selective diene hydrogenation Journal of Catalysis. ,vol. 327, pp. 54- 57 ,(2015) , 10.1016/J.JCAT.2015.04.017
Chun Wang, Haiyan Zhang, Cheng Feng, Shutao Gao, Ningzhao Shang, Zhi Wang, Multifunctional Pd@MOF core–shell nanocomposite as highly active catalyst for p-nitrophenol reduction Catalysis Communications. ,vol. 72, pp. 29- 32 ,(2015) , 10.1016/J.CATCOM.2015.09.004
Natalia Yu. Kozitsyna, Sergei E. Nefedov, Fedor M. Dolgushin, Natalia V. Cherkashina, Michael N. Vargaftik, Ilya I. Moiseev, Heterodimetallic PdII-based carboxylate-bridged complexes: Synthesis and structure of single-crystalline PdII–M (M=MnII, CoII, NiII, CuII, ZnII, NdIII, EuIII, CeIV) acetates Inorganica Chimica Acta. ,vol. 359, pp. 2072- 2086 ,(2006) , 10.1016/J.ICA.2006.01.027
Jesse M. Teo, Campbell J. Coghlan, Jack D. Evans, Ehud Tsivion, Martin Head-Gordon, Christopher J. Sumby, Christian J. Doonan, Hetero-bimetallic metal–organic polyhedra Chemical Communications. ,vol. 52, pp. 276- 279 ,(2016) , 10.1039/C5CC08336B
Zhenlan Fang, Bart Bueken, Dirk E. De Vos, Roland A. Fischer, Defect‐Engineered Metal–Organic Frameworks Angewandte Chemie. ,vol. 54, pp. 7234- 7254 ,(2015) , 10.1002/ANIE.201411540
Arnau Carné-Sánchez, Inhar Imaz, Mary Cano-Sarabia, Daniel Maspoch, A spray-drying strategy for synthesis of nanoscale metal–organic frameworks and their assembly into hollow superstructures Nature Chemistry. ,vol. 5, pp. 203- 211 ,(2013) , 10.1038/NCHEM.1569
A. Corma, H. García, F. X. Llabrés i Xamena, Engineering Metal Organic Frameworks for Heterogeneous Catalysis Chemical Reviews. ,vol. 110, pp. 4606- 4655 ,(2010) , 10.1021/CR9003924
H. Deng, S. Grunder, K. E. Cordova, C. Valente, H. Furukawa, M. Hmadeh, F. Gandara, A. C. Whalley, Z. Liu, S. Asahina, H. Kazumori, M. O'Keeffe, O. Terasaki, J. F. Stoddart, O. M. Yaghi, Large-Pore Apertures in a Series of Metal-Organic Frameworks Science. ,vol. 336, pp. 1018- 1023 ,(2012) , 10.1126/SCIENCE.1220131
Lauren E. Kreno, Kirsty Leong, Omar K. Farha, Mark Allendorf, Richard P. Van Duyne, Joseph T. Hupp, Metal–Organic Framework Materials as Chemical Sensors Chemical Reviews. ,vol. 112, pp. 1105- 1125 ,(2012) , 10.1021/CR200324T
TA Stephenson, SM Morehouse, Ao R Powell, JP Heffer, G Wilkinson, None, 667. Carboxylates of palladium, platinum, and rhodium, and their adducts Journal of the Chemical Society (Resumed). pp. 3632- 3640 ,(1965) , 10.1039/JR9650003632