A novel strategy for producing highly dispersed Pd particles on ZIF-8 through the occupation and unoccupation of carboxyl groups and its application in selective diene hydrogenation

作者: Xiaoqian Jia , Shihua Wang , Yu Fan

DOI: 10.1016/J.JCAT.2015.04.017

关键词:

摘要: Abstract We proposed a novel strategy for producing highly dispersed Pd particles on ZIF-8 via the anchoring effect of carboxyl groups incorporated into ligand ZIF-8. The as-synthesized nanoparticles supported in situ carboxyl-functionalized showed excellent activity and selectivity diene hydrogenation due to high dispersion interaction between groups. This method opens new simple route greatly improving nanoparticles.

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