Water-medium C–H activation over a hydrophobic perfluoroalkane-decorated metal-organic framework platform

摘要: Abstract The use of water as reaction medium in the heterogeneous activation C–H bonds has numerous advantages terms environmental benign, safety and cost efficiency impact. However, it is severely hampered because reactants are difficult to dissolve contact with active sites catalysts. Herein, we choose perfluoroalkane-functionalized mesoporous metal-organic framework (MOF) NU-1000 a hydrophobic platform encapsulate ultrafine palladium nanoparticles (Pd NPs) for water. resultant Pd NPs stabilized by perfluoroalkane exhibited high activity regioselectivity direct arylation indoles introduction chains into pores provides surfaces facilitate access guarantee activity.