Comparison of Needle Concentrator with SPME for GC Determination of Benzene, Toluene, Ethylbenzene, and Xylenes in Aqueous Samples

作者: P. Přikryl , R. Kubinec , H. Jurdáková , J. Ševčík , I. Ostrovský

DOI: 10.1365/S10337-006-0800-3

关键词:

摘要: A method of solventless extraction volatile organic compounds from aqueous samples has been developed and validated. new arrangement in which the internal volume a needle capillary adsorption trap is completely filled with Porapak Q, as adsorbent material, wet alumina, source desorptive water vapor flow, presented. The device used for head-space sampling benzene, toluene, ethylbenzene, xylenes (BTEX) compared solid-phase microextraction. Under same conditions analytical characteristics BTEX are better than those Limits detection quantification below 0.5 μ g L−1.

参考文章(16)
Róbert Kubinec, Victor G Berezkin, Renáta Górová, Gabriela Addová, Helena Mračnová, Ladislav Soják, Needle concentrator for gas chromatographic determination of BTEX in aqueous samples Journal of Chromatography B. ,vol. 800, pp. 295- 301 ,(2004) , 10.1016/J.JCHROMB.2003.09.009
P. Kuráň, L. Soják, Environmental analysis of volatile organic compounds in water and sediment by gas chromatography Journal of Chromatography A. ,vol. 733, pp. 119- 141 ,(1996) , 10.1016/0021-9673(95)01121-8
William K. Fowler, Christina H. Duffey, Herbert C. Miller, Modification of a gas chromatographic inlet for thermal desorption of adsorbent-filled sampling tubes Analytical Chemistry. ,vol. 51, pp. 2333- 2336 ,(1979) , 10.1021/AC50050A010
V.G. Berezkin, E.D. Makarov, B.V. Stolyarov, Needle-type concentrator and its application to the determination of pollutants Journal of Chromatography A. ,vol. 985, pp. 63- 65 ,(2003) , 10.1016/S0021-9673(02)01734-X
Jacek Namieśnik, Waldemar Wardencki, Solventless Sample Preparation Techniques in Environmental Analysis Journal of High Resolution Chromatography. ,vol. 23, pp. 297- 303 ,(2000) , 10.1002/(SICI)1521-4168(20000401)23:4<297::AID-JHRC297>3.0.CO;2-J
Yoshihiro Saito, Ikuo Ueta, Kenzo Kotera, Mitsuhiro Ogawa, Hiroo Wada, Kiyokatsu Jinno, In-needle extraction device designed for gas chromatographic analysis of volatile organic compounds Journal of Chromatography A. ,vol. 1106, pp. 190- 195 ,(2006) , 10.1016/J.CHROMA.2005.08.048
Heather Lord, Janusz Pawliszyn, Evolution of solid-phase microextraction technology Journal of Chromatography A. ,vol. 885, pp. 153- 193 ,(2000) , 10.1016/S0021-9673(00)00535-5
Mark E McComb, Richard D Oleschuk, Eugene Giller, Hyman D Gesser, None, Microextraction of volatile organic compounds using the inside needle capillary adsorption trap (INCAT) device Talanta. ,vol. 44, pp. 2137- 2143 ,(1997) , 10.1016/S0039-9140(97)00093-3
J. Lipinski, Automated solid phase dynamic extraction--extraction of organics using a wall coated syringe needle. Fresenius Journal of Analytical Chemistry. ,vol. 369, pp. 57- 62 ,(2001) , 10.1007/S002160000618