Present OH measurement limits and associated uncertainties

作者: D. J. Tanner , F. L. Eisele

DOI: 10.1029/94JD02609

关键词:

摘要: The first ion-assisted OH measurement instrument was developed and field tested in 1989. Since that time both technique have evolved substantially several potential interferences been investigated. Included among these are reactions could compete with the H2O/SO3 reaction, effect Of H2O on NO3− · HNO3/H2SO4 wall losses. These investigations also provided data of relevance to atmospheric ion neutral chemistry for two listed above, as well itself. Measurements made at Mauna Loa Observatory Hawaii show a diurnal variation tropospheric which spans more than 2 orders magnitude. Nighttime measurements revealed hydroxyl radicals 104 molecules cm−3 concentration range after dark.

参考文章(16)
Gaunlin Shen, Masako Suto, L. C. Lee, Reaction rate constant of SO3+ NH3in the gas phase Journal of Geophysical Research. ,vol. 95, pp. 13981- 13984 ,(1990) , 10.1029/JD095ID09P13981
DL Baulch, RA Cox, PJ Crutzen, RF Hampson Jr, JA Kerr, J Troe, RT Watson, None, Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement I CODATA Task Group on Chemical Kinetics Journal of Physical and Chemical Reference Data. ,vol. 11, pp. 327- 496 ,(1982) , 10.1063/1.555664
D. L. Baulch, R. A. Cox, R. F. Hampson, J. A. Kerr (Chairman), J. Troe, R. T. Watson, Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement II. CODATA Task Group on Gas Phase Chemical Kinetics Journal of Physical and Chemical Reference Data. ,vol. 13, pp. 1259- 1380 ,(1984) , 10.1063/1.555721
F. L. Eisele, Identification of tropospheric ions Journal of Geophysical Research. ,vol. 91, pp. 7897- 7906 ,(1986) , 10.1029/JD091ID07P07897
A. A. Viggiano, Robert A. Morris, F. Dale, John F. Paulson, Tropospheric reactions of H+(NH3)m(H2O)nwith pyridine and picoline Journal of Geophysical Research. ,vol. 93, pp. 9534- 9538 ,(1988) , 10.1029/JD093ID08P09534
Xiuyan Wang, Y. G. Jin, Masako Suto, L. C. Lee, H. E. O’Neal, Rate constant of the gas phase reaction of SO3 with H2O Journal of Chemical Physics. ,vol. 89, pp. 4853- 4860 ,(1988) , 10.1063/1.455680
Y. Lu, M. A. K. Khalil, Model calculations of night-time atmospheric OH Tellus B. ,vol. 44, pp. 106- 113 ,(1992) , 10.3402/TELLUSB.V44I2.15431