The Intermolecular Hydrogen Bonding between Methanol and Triethylamine in Various States

摘要: The intermolecular hydrogen bond energy between methanol and triethylamine was determined by infrared studies in the vapor state solutions. It also found that, with an increase dielectric constant, e, of solvents, free O–H stretching band shifts to a lower frequency, molar absorptivity this increases, system decreases. As is well known, hydrogen-bonded mainly stabilized contribution two resonating structures, non-bonded structure charge-transfer structure. seems probable that weight latter for relatively weak complex small. Therefore, if energies both structures are assumed be electrostatic interaction, may expected reciprocal constant environment. This actually true within limits experimental error few found...